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Super austenitic stainless steel with low precipitation phase precipitation and method for its preparation and heat treatment

A technology of austenitic stainless steel and heat treatment method, applied to super austenitic stainless steel with low precipitation phase precipitation and its preparation and heat treatment fields, can solve the problems of easy solidification segregation, deterioration of steel properties, etc., to promote enrichment and inhibit precipitation. , Improve the effect of thermal processing and service performance

Active Publication Date: 2022-07-22
TAIYUAN UNIV OF TECH +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] However, the solubility of B in austenitic stainless steel is only 0.018%-0.026%, and the solid solution amount of rare earth Ce in steel is basically several to dozens of ppm
When added in excess, it is very easy to solidify and segregate, and will form larger-sized metal borides and rare earth inclusions, which will deteriorate the performance of steel

Method used

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  • Super austenitic stainless steel with low precipitation phase precipitation and method for its preparation and heat treatment
  • Super austenitic stainless steel with low precipitation phase precipitation and method for its preparation and heat treatment
  • Super austenitic stainless steel with low precipitation phase precipitation and method for its preparation and heat treatment

Examples

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Effect test

Embodiment 1

[0030] Example 1: Preparation of B, Ce microalloyed super austenitic stainless steel

[0031] Using a 50kg induction furnace to smelt the super austenitic stainless steel of the present invention specifically includes the following steps:

[0032] 1) Smelt in a 50Kg vacuum induction furnace according to the alloy composition ratio shown in Table 1, cast it into an ingot of 120×100×500mm in a vacuum state, and take it out from the mold after the ingot is air-cooled;

[0033] 2) The ingot was kept at 1200°C for 10h with a resistance heating furnace, cooled to room temperature in air, and then the ingot was heated to 1230°C with the furnace and kept for 30min, and then rolled on a Φ550 type hot rolling mill to a thickness of 17mm. steel plate.

[0034] Table 1. Composition of B and Ce microalloyed super austenitic stainless steels

[0035]

[0036] After grinding, polishing and corroding the sample, its structure and morphology were observed by scanning electron microscope, ...

Embodiment 2

[0037] Example 2: Precipitation phase distribution after high temperature aging treatment of super austenitic stainless steel with low precipitation phase precipitation.

[0038] The low precipitation of the grain boundary σ phase during high temperature aging of B and Ce microalloyed super austenitic stainless steel is achieved by staged rate-controlled cooling and low-temperature aging treatment, which specifically includes the following steps:

[0039] 1) Solution treatment: A 15×15×12mm sample was cut from the super austenitic stainless steel plate prepared according to Example 1, the temperature of the box furnace was raised to 1200°C, and the sample was placed in a 1200°C box furnace for heat preservation and solid solution Treatment for 0.5h; all solution treatments were carried out in an inert atmosphere.

[0040] 2) Staged rate-controlled cooling treatment: Cool the solution-treated samples to 1100°C at a rate of 90°C / min, and then air-cool to room temperature.

[00...

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Abstract

The purpose of the present invention is to provide a preparation and heat treatment method of super austenitic stainless steel with low precipitation phase precipitation, which belongs to the technical field of preparation and application of super austenitic stainless steel, and can obviously suppress the precipitation of Cr-rich and Mo-rich hard and brittle σ phases, thereby To improve the corrosion resistance of super austenitic stainless steel, molten steel is smelted according to the set composition and cast into a billet. After high temperature homogenization treatment, hot rolling is carried out; That is, the sample is cooled from the solution temperature to 1100-1150°C at a speed of 60-90°C / min, and then air-cooled to room temperature; then heated to 280-320°C, kept for 0.5-1h for low-temperature aging treatment, and finally air-cooled. The super austenitic stainless steel prepared by the invention can effectively suppress the problem of easy precipitation of brittle phase along the grain boundary at high temperature due to the high content of alloy elements (Cr, Mo, etc.), improve the brittleness of the grain boundary and improve the thermoplasticity of the super austenitic stainless steel.

Description

technical field [0001] The invention belongs to the technical field of preparation and application of super austenitic stainless steel, in particular to a super austenitic stainless steel with low precipitation phase precipitation and a preparation and heat treatment method thereof. Background technique [0002] Super austenitic stainless steel (hereinafter referred to as super austenitic) is a kind of stainless steel with ultra-low C, high Mo, Cr, Ni and N elements. The combination of Cr, Mo and N elements makes the material resistant to pitting corrosion and intergranular corrosion. Excellent, its corrosion resistance is comparable to that of high corrosion-resistant nickel-based alloys, and it has a cost advantage. It has a unique role in equipment used in harsh corrosive environments such as marine, environmental protection, and chemical industries. With the in-depth advancement of the "Made in China 2025 Plan" in various industries, the demand for such materials will in...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C22C38/54C22C38/44C22C38/42C22C38/02C22C38/04C21D1/74C21D8/02
CPCC22C38/54C22C38/44C22C38/42C22C38/001C22C38/02C22C38/04C22C38/005C21D1/74C21D8/0226C21D8/0247C21D2211/001
Inventor 梁小红韩培德李花兵姜周华王剑李玉平董楠
Owner TAIYUAN UNIV OF TECH