Liquid crystal aligning agent, liquid crystal alignment film, display substrate, liquid crystal display device, and polyimide
A technology of liquid crystal alignment agent and polyamic acid, which is applied in liquid crystal materials, instruments, organic chemistry, etc., and can solve problems such as easy debris of liquid crystal alignment film and poor display of liquid crystal display substrates
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experiment example 1
[0251] In Experimental Example 1, two kinds of dianhydrides and diamines that have been mass-produced at present are used. The structural formulas of dianhydrides and diamines are shown in the following formula (i) and the following formula (ii).
[0252]
[0253] The preparation method is as follows:
[0254] S1. Add a certain amount of N-methylpyrrolidone or DMF into the reactor, pass nitrogen protection into the reactor, add bisanhydride (i) and diamine (ii) to mix, and under stirring, control the temperature of the reactor Polymerization is carried out at a temperature of 15-30° C. and a reaction time of 4-6 hours to obtain polyimide A.
[0255] S2, the purified polyamic acid A with a certain solvent (by GBL (γ-butyrrolactone, γ-butyrolactone), NMP (N-methyl-2-pyrrolidone, N-methylpyrrolidone), BC (Butyl carbitol (Butyl Di-glycol), diethylene glycol monobutyl ether) and DAA (Diacetone alcohol, diacetone alcohol) are diluted according to the ratio of 50:30:10:10), and t...
experiment example 2
[0262] Experimental Example 2 adopts the following various experimental schemes. The preparation process of the following experimental scheme is basically the same as that of Experimental Example 1. The difference is that the experimental raw materials used in Experimental Example 2 are the following dianhydrides and diamines provided by the present disclosure.
[0263] The first experimental scheme, the experimental raw material is the first bisanhydride shown in the following formula (I) and the first diamine shown in the following formula (II), wherein R 1 and R 2 are selected from methyl.
[0264] The second experimental scheme, the experimental raw material is the first bisanhydride shown in the following formula (I) and the first diamine shown in the following formula (III), wherein R 1 and R 2 are selected from methyl.
[0265] The third test scheme, the experimental raw material is the first dianhydride shown in the following formula (I), the first diamine shown in ...
experiment example 3
[0276] Experimental Example 3 adopts the following various experimental schemes, the following experimental schemes are basically the same as Experimental Example 2, the difference is that the experimental raw materials used in Experimental Example 3 also contain hydrophobic groups and hydrophilic groups.
[0277] The first experimental scheme, the experimental raw material is the first bisanhydride shown in the following formula (I) and the first diamine shown in the following formula (II), wherein R 1 and R 2 are selected from methyl.
[0278] The second experimental scheme, the experimental raw material is the first bisanhydride shown in the following formula (I) and the first diamine shown in the following formula (III), wherein R 1 and R 2 are selected from methyl.
[0279] The third test scheme, the experimental raw material is the first dianhydride shown in the following formula (I), the first diamine shown in the following formula (II) and the second dianhydride sho...
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