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Catalytic cracking catalyst and preparation method thereof

A catalytic cracking and catalyst technology, applied in catalyst activation/preparation, catalytic cracking, physical/chemical process catalysts, etc., can solve the problems of high energy consumption, high loss, and complex catalytic cracking catalyst preparation

Pending Publication Date: 2022-05-06
CHINA PETROLEUM & CHEM CORP +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0010] The purpose of the present invention is to provide a preparation method of a catalytic cracking catalyst and a catalyst prepared therefrom in order to overcome the problems of complex preparation of catalytic cracking catalysts, large energy consumption, and many losses in the prior art, wherein, in the catalytic cracking catalysts The molecular sieve containing rare earth elements, in this method, the molecular sieve containing rare earth elements does not need to be roasted during preparation, the preparation process is simple, and the catalytic cracking catalyst obtained has excellent catalytic performance

Method used

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  • Catalytic cracking catalyst and preparation method thereof
  • Catalytic cracking catalyst and preparation method thereof
  • Catalytic cracking catalyst and preparation method thereof

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preparation example Construction

[0044] In order to achieve the above object, a first aspect of the present invention provides a method for preparing a catalyst cracking catalyst, the method comprising:

[0045] 1) making the sodium-type molecular sieve and the solution containing the ammonium root ion carry out the first ion exchange reaction, and obtain the molecular sieve after the ammonium root ion exchange;

[0046] 2) Under microwave conditions, the ammonium ion-exchanged molecular sieve and the solution containing rare earth element ions are subjected to a second ion exchange reaction to obtain a molecular sieve containing rare earth elements;

[0047] 3) After beating the rare earth element-containing molecular sieve obtained in step 2) with clay, binder, water and inorganic acid to form a colloid, the obtained colloid is dried and calcined.

[0048] The inventors of the present invention have found that, firstly, the ammonium ion is used to exchange the sodium ions in the sodium-type molecular sieve,...

Embodiment 1

[0106] 1) NaY molecular sieve is mixed with ammonium ion concentration in ammonium chloride aqueous solution of 2mol / L, with respect to 1L ammonium chloride aqueous solution, the addition amount of NaY molecular sieve is 200g, adjusts pH with dilute hydrochloric acid solution (concentration is 5% by weight) After reaching 5.5, heat the above mixed solution to 70°C, and stir at this temperature for 30 minutes, then filter, wash the product with 5 times the volume of deionized water after filtration, and then dry it at 150°C for 6 hours to obtain ammonium ion-exchanged Molecular sieve;

[0107] 2) the molecular sieve after the ammonium ion exchange that step 1) obtains and total concentration are lanthanum chloride and cerium chloride aqueous solution (wherein, lanthanum chloride concentration is 0.2mol / L, and cerium chloride concentration is 0.3mol / L) mixing and beating, relative to 1L lanthanum chloride aqueous solution, the amount of molecular sieve after ammonium ion exchang...

Embodiment 2

[0115] 1) NaY molecular sieve is mixed with ammonium ion concentration in ammonium chloride aqueous solution of 2mol / L, with respect to 1L ammonium chloride aqueous solution, the addition amount of NaY molecular sieve is 200g, adjusts pH with dilute hydrochloric acid solution (concentration is 5% by weight) After reaching 6, heat the above mixed solution to 60°C, and stir at this temperature for 20 minutes, then filter, wash the obtained product with 5 times the volume of deionized water after filtration, and then dry at 150°C for 6 hours to obtain ammonium ion exchanged Molecular sieve;

[0116] 2) the molecular sieve after the ammonium ion exchange that step 1) obtains and total concentration are lanthanum chloride and cerium chloride aqueous solution (wherein, lanthanum chloride concentration is 0.04mol / L, and cerium chloride concentration is 0.06mol / L) mixing and beating, relative to 1L lanthanum chloride aqueous solution, the amount of molecular sieve after ammonium ion e...

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Abstract

The invention relates to the field of catalytic cracking catalyst preparation, and discloses a catalytic cracking catalyst and a preparation method thereof. The method comprises the following steps: 1) carrying out first ion exchange reaction on a sodium molecular sieve and a solution containing ammonium ions to obtain a molecular sieve subjected to ammonium ion exchange; 2) under a microwave condition, carrying out a second ion exchange reaction on the molecular sieve subjected to ammonium ion exchange and a solution containing rare earth element ions to obtain a molecular sieve containing rare earth elements; and 3) pulping the rare earth element-containing molecular sieve obtained in the step 2), clay, a binder, water and inorganic acid into gel, and drying and roasting the obtained gel. By adopting the method provided by the invention, roasting is not needed when the molecular sieve containing the rare earth elements is prepared, the preparation process is simple, and the catalytic cracking catalyst is excellent in catalytic performance.

Description

technical field [0001] The invention relates to the field of catalytic cracking catalyst preparation, in particular to a catalytic cracking catalyst and a preparation method thereof. Background technique [0002] The petroleum refining industry is an important pillar of the national economy, with a long industrial chain and a wide coverage of downstream products, which are closely related to the development of the national economy and people's lives. The most important refining method in the petroleum refining process is catalytic cracking technology, and catalytic cracking catalyst is the core key technology of catalytic cracking technology. With the heavy and inferior quality of crude oil in the world, as well as the increasing demand for clean oil products and increasingly stringent environmental protection requirements, people are forced to develop catalytic cracking with higher catalytic activity, stability and lower sodium content. Catalyst to obtain higher conversion...

Claims

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Application Information

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IPC IPC(8): B01J29/08B01J29/40B01J29/70B01J35/10B01J37/06B01J37/30C10G11/05
CPCB01J37/30B01J29/087B01J29/088B01J29/405B01J29/7053B01J29/7057B01J37/06C10G11/05B01J2229/186C10G2300/70C10G2400/02B01J35/617Y02P20/52
Inventor 李腾飞杨柳任靖吕岩殷喜平沈刚武永安李柯志赵保槐韩帅胡海强
Owner CHINA PETROLEUM & CHEM CORP
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