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Method and device for removing cations in steam water of power station

A cation and power station technology, applied in the field of cation removal in soda water in power stations, can solve the problems of inaccurate measurement of hydrogen conductivity, many measurement blind spots, intermittent output data of the hydrogen conductivity measurement system, etc., to ensure timeliness and accuracy, use Significant effect, avoid the effect of replacement

Pending Publication Date: 2022-05-13
华能南京燃机发电有限公司 +1
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Problems solved by technology

[0003] 1) In order to ensure the accuracy of sampling, the ion exchange resin column used needs to be replaced regularly; even if the strategy of not replacing is adopted, the ion exchange resin needs to be regenerated regularly, and the cleaning time and cleaning quality after regeneration will be serious. Affect the timeliness and accuracy of hydrogen conductivity measurement
[0004] 2) When cleaning, regenerating or replacing the ion exchange resin, the output data of the hydrogen conductivity measurement system is basically intermittent, and the accurate measurement of the hydrogen conductivity has the most direct relationship with the concentration of cations in the water quality, and frequent start and stop will lead to The hydrogen conductivity measurement is inaccurate, and there are many measurement blind spots
In addition, due to the frequent start-up and shutdown of gas turbine power plants, the ion-exchange resin column needs to be washed for a long time before the reading can be stabilized every time the start-up is started, which cannot effectively guide the adjustment of the water conditions during start-up

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  • Method and device for removing cations in steam water of power station

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Embodiment Construction

[0024] The invention provides a method for removing cations from soda water in a power station. The method includes the step of removing cations, and the removal of cations is carried out by using a continuous electric regeneration module. The continuous electric regeneration module used in the present invention is an electric regeneration cation exchanger, which uses the voltage at both ends of the electrodes to move charged ions in water, and cooperates with ion exchange resins and selective membranes to accelerate ion movement, effectively removing cations in water; The hydrogen ions in it regenerate a very small amount of special resin in real time and dynamically, so that the resin in it always maintains a hydrogen state, and there is no need to replace the regenerated resin (the schematic diagram is shown in figure 1 shown), that is, by constant current electrolysis of water to generate H + and OH - Ions, continuously regenerate the cation resin in the electric regenera...

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Abstract

The invention belongs to the technical field of cation removal, and relates to a method and device for removing cations in steam water of a power station, and the device comprises a water body circulation pipeline, a continuous electric regeneration module and a hydrogen conductivity meter; the continuous electric regeneration module is arranged on the water circulation pipeline; and the hydrogen conductivity meter is connected with the continuous electric regeneration module. The invention provides the method and the device for removing the cations in the steam water of the power station, which are high in hydrogen conductivity measurement accuracy.

Description

technical field [0001] The invention belongs to the technical field of cation removal, and relates to a method and a device for removing cations from soda water in power stations. Background technique [0002] In order to prevent metal corrosion in the thermal system of thermal power plants, ammonia treatment is commonly used in feed water. Ammonia is a volatile substance, except that it reacts with carbonic acid and consumes part of it, it basically stays in the circulation of the thermal system. The ammonia content in the system is about 1-3mg / L. When the unit is in normal operation, the content of other impurity components in desalted water, condensed water, and steam is basically at the microgram level. This milligram-level ammonia causes ordinary conductivity detection to fail to reflect other impurity components, so through the cation exchange column. After the ammonium root is removed, the conductivity can accurately reflect the content of anions in the water vapor. ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/469G01D21/02
CPCC02F1/4695G01D21/02C02F2209/40C02F2209/05C02F2303/14
Inventor 阴海强奚新国谷睿轩田利袁源刘家澍戴鑫曹殿尧苏通张龙明候苏宁
Owner 华能南京燃机发电有限公司
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