Unlock instant, AI-driven research and patent intelligence for your innovation.

Preparation method of large biological functional agent containing active ingredients of navel oranges

A technology of active ingredients and functional agents, which is applied in the field of preparation of large biological functional agents, can solve the problems of poor fatliquor filling, poor leather strength, and reduce leather haze, so as to improve tear strength, tensile strength, and The effect of antimicrobial properties

Inactive Publication Date: 2022-06-24
BYHERB BIGBIO TECH QINGDAO CO LTD
View PDF1 Cites 1 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] CN112626292A discloses a low-fogging leather synthetic fatliquor and its preparation method and application. By modifying palm oil and adding high-boiling mineral oil, the fog value of leather can be reduced, and it can be applied to leather such as car interior seats. , but the addition of a large amount of vegetable oil will result in poor light resistance, the addition of mineral oil and vegetable oil can improve the light resistance to a certain extent, but the filling performance of mineral oil is poor, and the strength of the leather after fatliquoring is slightly worse
[0005] In the current prior art, although the low-fogging fatliquoring agent compounded with vegetable oil and mineral oil can achieve a low fogging effect and improve light resistance to a certain extent, it will lead to poor filling of the fatliquoring agent and lead to a loss of leather strength. Low especially the tear strength and tensile strength, currently there are no articles or reports that can address the shortcomings of this type of fatliquor

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0041] (1) Preparation of modified palm oil

[0042] Mix palm oil with p-tert-butylphenyl glycidyl ether, add dicyclohexyl peroxydicarbonate, heat up to 70°C under nitrogen protection and stir for 150min to obtain preliminary modified palm oil, and mix hydrogen-containing silicone oil with preliminary modified palm oil. mixed with palm oil, heated to 65℃, stirred at -0.05Mpa for 30min, then added Raney nickel catalyst, heated to 75℃, stirred for 90min, removed the catalyst to obtain modified palm oil;

[0043] Described palm oil is 58 degree palm oil;

[0044] The mass ratio of described palm oil and p-tert-butylphenyl glycidyl ether is 3:2;

[0045] The mass ratio of described dicyclohexyl peroxydicarbonate and palm oil is 1:50;

[0046] The hydrogen content of the hydrogen-containing silicone oil is 0.15%;

[0047] The mass ratio of the hydrogen-containing silicone oil to the preliminary modified palm oil is 1:3;

[0048] The nickel content of the Raney nickel catalyst i...

Embodiment 2

[0075] (1) Preparation of modified palm oil

[0076] Mix palm oil with p-tert-butylphenyl glycidyl ether, add dicyclohexyl peroxydicarbonate, heat up to 65°C under nitrogen protection and stir for 180min to obtain preliminary modified palm oil, mix hydrogen-containing silicone oil with preliminary modified palm oil. mixed with palm oil, heated to 60℃, stirred at -0.04Mpa for 40min, then added Raney nickel catalyst, heated to 70℃, stirred for 100min, removed the catalyst to obtain modified palm oil;

[0077] Described palm oil is 58 degree palm oil;

[0078] The mass ratio of described palm oil and p-tert-butylphenyl glycidyl ether is 2.5:2;

[0079] The mass ratio of described dicyclohexyl peroxydicarbonate and palm oil is 1:40;

[0080] The hydrogen content of the hydrogen-containing silicone oil is 0.12%;

[0081] The mass ratio of the hydrogen-containing silicone oil to the preliminary modified palm oil is 1:2.5;

[0082] The nickel content of the Raney nickel catalyst ...

Embodiment 3

[0109] (1) Preparation of modified palm oil

[0110] Mix palm oil with p-tert-butylphenyl glycidyl ether, add dicyclohexyl peroxydicarbonate, heat up to 75°C under nitrogen protection and stir for 130min to obtain preliminary modified palm oil, mix hydrogen-containing silicone oil with preliminary modified palm oil. mixed with palm oil, heated to 70°C, stirred at -0.06Mpa for 25min, then added Raney nickel catalyst, heated to 80°C and stirred for 80min, removed the catalyst to obtain modified palm oil;

[0111] Described palm oil is 58 degree palm oil;

[0112] The mass ratio of described palm oil and p-tert-butylphenyl glycidyl ether is 3.5:2;

[0113] The mass ratio of described dicyclohexyl peroxydicarbonate and palm oil is 1:60;

[0114] The hydrogen content of the hydrogen-containing silicone oil is 0.17%;

[0115] The mass ratio of the hydrogen-containing silicone oil to the preliminary modified palm oil is 1:3.5;

[0116] The nickel content of the Raney nickel catal...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

PropertyMeasurementUnit
Tear strengthaaaaaaaaaa
Tear strengthaaaaaaaaaa
Tensile strengthaaaaaaaaaa
Login to View More

Abstract

The invention discloses a preparation method of a large biological functional agent containing active ingredients of navel oranges. The preparation method comprises the following steps: preparing modified palm oil, preparing modified mineral oil, preparing modified cellulose and preparing a fatting agent. When the large biological functional agent containing the navel orange active component is used for fat liquoring of leather, the fog value of the leather can be reduced, and the fog value tested at 100 DEG C for 16 hours by a mass method is 0.43-0.45 mg; the large biological functional agent containing the navel orange active ingredients, prepared by the invention, has good filling performance on the leather fatliquor, and the absorption rate of the fatliquor is 98.3-98.6%; when the large biological functional agent containing the navel orange active component is used for fat liquoring of leather, the tearing strength of the leather can be improved, the original tearing strength of the leather is 61.2 N / mm, and the tearing strength after fat liquoring is 67.5-68.5 N / mm.

Description

technical field [0001] The invention relates to a preparation method of a large biological functional agent containing navel orange active components, and belongs to the technical field of leather fatliquor. Background technique [0002] Fatliquoring (also known as oiling) in leather production is the process of treating leather with grease or fatliquor under certain technological conditions, so that the leather absorbs a certain amount of grease and gives the leather certain physical, mechanical properties and performance. Fatliquoring can make the fibers inside the leather be wrapped by lubricating grease through chemical and physical action, or the surface of the fibers has affinity with a large number of "oily" molecules, balance the surface energy of the leather fibers, and transform the original high-energy surface into a low-energy surface. Increase the mutual mobility between fibers, thereby preventing the leather from hardening and cracking, and making the leather h...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C14C3/14C14C9/02C08B15/06
CPCC14C9/02C14C3/14C08B15/06
Inventor 汪培育黄效华甄丽
Owner BYHERB BIGBIO TECH QINGDAO CO LTD