Electrochemical element, and module and battery comprising same
An electrochemical element and element technology, applied in the field of energy storage, can solve problems such as deterioration of solid electrolyte characteristics
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Embodiment 1
[0130] In order to verify the chemical protection of the enclosures according to the invention, experiments were carried out with pouches of selected materials.
[0131] By mechanosynthesis (500rpm, 20h), from the precursor Li 2 S.P 2 S 5 and LiCl are produced in stoichiometric proportions with Li 6 PS 5 Argyrodite sulfide electrolyte of Cl composition. The ionic conductivity of this electrolyte was measured by impedance spectroscopy on pellets compressed at 250 MPa in a pressurized cell and reached 1 mS / cm at room temperature (RT).
[0132] On the other hand, the obtained sulfide electrolyte powder was compressed at 250 MPa to form pellets having a thickness of 400 μm and a diameter of 10 mm.
[0133] A sheet of dyMAT ClrPYE MONO (285 μm - sold by COVEME Corporation) and a sheet of ultra-barrier solar film (203 μm - sold by 3M TM Company sales) were placed on both sides of the sulfide electrolyte pellets to make an outer cover (Example #2). The edges of the cover thus ...
Embodiment 2
[0139] Considering the sensitivity of the materials used to ambient air, the following operations are performed in an environment with a dew point below -50°C, and can be performed in an argon atmosphere.
[0140]The sulfide electrolyte powder (as produced in Example 1) was cold compressed (200 MPa) in a granulator to form pellets ('electrolyte layer') with a thickness of about 400 μm. The sulfide electrolyte powder and the active cathode material (NCA) powder were mixed with a mortar and pestle in a mass ratio NCA:SE of 70:30 until uniform distribution was achieved. This mixture (making up the positive electrode) was added to one side of the electrolytic layer in the granulator, and the assembly was compressed again (200 MPa) to form dense solid pellets (the thickness of the positive electrode was close to 100 μm). On the other side of the electrolytic layer, a negative electrode composed of graphite and solid electrolyte powder was added, and the graphite and solid electroly...
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