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Unsaturated polyester resin composite material with excellent flame retardant property

A technology of polyester resin and composite materials, which is applied in the direction of foam dispersion/prevention, can solve the problems of limited application, and achieve the effects of wide application scenarios, high fire safety, and excellent flame retardancy

Pending Publication Date: 2022-08-09
NANJING INST GENERAL INST OF COAL SCI
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the limiting oxygen index (LOI) of UP is only 19.0% to 20.0%, which is a flammable material. At the same time, due to its high content of carbon and hydrogen elements and more aromatic side groups in the main chain, it will be accompanied by concentrated The generation of smoke and toxic gases greatly limits its application in many fields

Method used

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  • Unsaturated polyester resin composite material with excellent flame retardant property
  • Unsaturated polyester resin composite material with excellent flame retardant property
  • Unsaturated polyester resin composite material with excellent flame retardant property

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0035] Mix 100g of 191-type unsaturated polyester resin, 3g of expandable graphite and 7g of ammonium polyphosphate into which the merchant has added the accelerator (5% cobalt naphthenate solution, the addition amount is 1g), and then stir with a glass rod until there is no Obvious lumps, then at room temperature (25-30°C), use a stirrer to quickly stir for 30min, add 1g of curing agent and continue to stir for 2-3min, stir well to obtain a homogeneous solution, put the obtained solution in a vacuum drying box for vacuum After defoaming for 10 minutes, it was poured into the prepared mold and cured at 40°C for 2 hours and 80°C for 2 hours. After the curing is completed, the mold is cooled to room temperature and demolded to obtain an unsaturated polyester resin composite material with excellent flame retardancy.

Embodiment 2

[0037] Mix 100g of 191-type unsaturated polyester resin, 3g of expandable graphite and 7g of ammonium polyphosphate into which the merchant has added the accelerator (5% cobalt naphthenate solution, the addition amount is 1g), and then stir with a glass rod until there is no Obvious lumps, then use a stirrer to quickly stir for 30min at normal temperature (25-30℃), then take out the solution and place it in a vacuum drying box for the first vacuum defoaming treatment for about 10min (depending on the amount of bubbles After the bubbles are eliminated, add 1g of curing agent and continue to stir for 2-3min. After stirring evenly, a homogeneous solution is obtained. The obtained solution is placed in a vacuum drying box for secondary vacuum defoaming for 2-3min. The solution after elimination was poured into the prepared mold, and cured at 40°C for 2 hours and at 80°C for 2 hours. After the curing is completed, after the mold is cooled to room temperature, the mold is demolded t...

Embodiment 3

[0039] Mix 100g of 191-type unsaturated polyester resin, 2g of expandable graphite, and 7g of ammonium polyphosphate into which the merchant has added the accelerator (5% cobalt naphthenate solution, the addition amount is 1g), and then stir with a glass rod until there is no Obvious lumps, then use a stirrer to quickly stir for 30min at normal temperature (25-30℃), then take out the solution and place it in a vacuum drying box for the first vacuum defoaming treatment for about 10min (depending on the amount of bubbles After the bubbles are eliminated, add 1g of curing agent and continue to stir for 2-3min. After stirring evenly, a homogeneous solution is obtained. The obtained solution is placed in a vacuum drying box for secondary vacuum defoaming for 2-3min. The solution after elimination was poured into the prepared mold, and cured at 40°C for 2 hours and at 80°C for 2 hours. After the curing is completed, after the mold is cooled to room temperature, the mold is demolded ...

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Abstract

The invention discloses an unsaturated polyester resin composite material with excellent flame retardant property and a preparation method thereof. The unsaturated polyester resin composite system comprises a 191 type unsaturated polyester resin monomer, a curing agent, an accelerant and a flame retardant. Wherein the flame retardant comprises expandable graphite (EG) and ammonium polyphosphate (APP). Wherein 100 parts by weight of unsaturated polyester resin monomer, 1-2 parts by weight of curing agent, 0.5-3 parts by weight of accelerant, 1.5-3 parts by weight of expansible graphite and 6-7 parts by weight of ammonium polyphosphate are cured at 40-80 DEG C to obtain the unsaturated polyester resin. The flame-retardant unsaturated polyester resin material disclosed by the invention has very excellent flame-retardant property, and the comprehensive mechanical property is superior to that of the single addition of the same amount of expansible graphite or ammonium polyphosphate, so that the material can meet the requirements of more use scenes.

Description

technical field [0001] The invention relates to an unsaturated polyester resin composite material with excellent flame retardant performance and a preparation method thereof, belonging to the field of composite materials and preparation thereof. Background technique [0002] As a kind of thermosetting resin, unsaturated polyester resin (UP) has excellent mechanical properties, electrical properties and chemical corrosion resistance. It is usually widely used in ships, automobile industry, building materials, electrical products and rails in the form of FRP. transportation and other industries. However, the limiting oxygen index (LOI) of UP is only 19.0% to 20.0%, which is a flammable material. At the same time, due to its high carbon and hydrogen content and more aromatic side groups in the main chain, the combustion process will be accompanied by concentrated The generation of smoke and toxic gases greatly limits its application in many fields. Therefore, researching the ...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C08L67/06C08K3/32C08K9/00C08K3/04B01D19/02
CPCC08K3/32C08K9/00C08K3/04B01D19/02C08K2003/323C08L2201/02C08L67/06
Inventor 闵付松刘钧源陶三宝锁卫郎潮王子凡蔡承志李申怡
Owner NANJING INST GENERAL INST OF COAL SCI