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Process for preparing Large ratio surface bata-type aluminium hydroxide

A technology of aluminum hydroxide and large specific surface is applied in the field of preparation of aluminum hydroxide, which can solve the problem that the specific surface of the product is not ideal, and achieve the effect of easy implementation and high purity

Active Publication Date: 2007-03-21
GUIZHOU BRANCH CHINA ALUMINUM IND
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  • Abstract
  • Description
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  • Application Information

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Problems solved by technology

[0004] In addition, the Chinese patent application number 00132219.2 proposes a method for producing β-type aluminum hydroxide. The refined solution of sodium aluminate obtained by the soda-lime sintering method has an alumina content of 85-100 g / l, and the solution is caustic. The ratio (αk) is 1.4~1.6, and the carbon dioxide gas with a concentration of 35~40% is passed in at 40~70°C, and the gas flow rate is 100~150m 3 / hour·m 3 solution, the ventilation time is 60-90 minutes, the decomposition rate is 88-90%, and the content of the obtained product β-type aluminum hydroxide is more than 97%, but the specific surface of the product is not very ideal

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  • Process for preparing Large ratio surface bata-type aluminium hydroxide

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Embodiment 1

[0016] The preparation method of the large specific surface β-type aluminum hydroxide described in the present invention uses the sodium aluminate refined solution obtained by the soda lime sintering method as a raw material, and its composition is that the alumina content is 100g / l, and αk1.44 is diluted with distilled water to The alumina content is 65g / l, and at 34°C, carbon dioxide gas with a concentration of 36% is passed in, and the gas flow rate is 30m 3 / hour·m 3 Solution, after 25 minutes of neutralization reaction, stop feeding carbon dioxide gas, and continue feeding carbon dioxide gas for 65 minutes after 20 minutes, the decomposition rate is 88%. Separate the liquid from the solid, wash and dry the solid to obtain β-type aluminum hydroxide, the content of the product β-type aluminum hydroxide is 90.5%, and the specific surface is 310m 2 / g, and its chemical composition is shown in Table 1.

Embodiment 2

[0018] The preparation method of the large specific surface β-type aluminum hydroxide described in the present invention uses the sodium aluminate refined solution obtained by the soda lime sintering method as a raw material, and its composition is that the alumina content is 100g / l, and αk1.44 is diluted with distilled water to The alumina content is 61g / l, and at 30°C, carbon dioxide gas with a concentration of 36% is passed in, and the gas flow rate is 35m 3 / hour·m 3 Solution, after 20 minutes of neutralization reaction, stop feeding carbon dioxide gas, and continue feeding carbon dioxide gas for 60 minutes after 20 minutes, the decomposition rate is 84%. Separating the liquid from the solid, washing and drying the solid to obtain β-type aluminum hydroxide, the content of the product β-type aluminum hydroxide is 92.4%, and the specific surface is 330m 2 / g, and its chemical composition is shown in Table 1.

Embodiment 3

[0020] The preparation method of the large specific surface β-type aluminum hydroxide described in the present invention uses the sodium aluminate refined solution obtained by the soda lime sintering method as a raw material, and its composition is that the alumina content is 100g / l, and αk1.44 is diluted with distilled water to The alumina content is 56g / l, and at 25°C, carbon dioxide gas with a concentration of 40% is passed in, and the gas flow rate is 40m 3 / hour·m 3 Solution, after 20 minutes of neutralization reaction, stop feeding carbon dioxide gas, continue feeding carbon dioxide gas after 20 minutes for 55 minutes, the decomposition rate is 80%. Separate the liquid from the solid, wash and dry the solid to obtain β-type aluminum hydroxide. The content of the product β-type aluminum hydroxide is 93.2%, and the specific surface is 382m 2 / g, and its chemical composition is shown in Table 1.

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Abstract

A process for preparing beta-aluminum hydroxide with large specific surface area includes such steps as intermittently filling CO2 gas in the solution of sodium aluminate, liquid-solid separation, washing, and baking.

Description

technical field [0001] The invention relates to a method for preparing large specific surface β-type aluminum hydroxide, which belongs to the preparation technology of aluminum hydroxide. Background technique [0002] β-type aluminum hydroxide is mainly used as a catalyst raw material. The larger the specific surface, the larger the specific surface of the catalyst, the larger the contact surface between the catalyst and the catalyzed substance, and the faster the catalytic reaction speed. In production, the amount of catalyst can be reduced, the production cost can be reduced, or the chemical reaction time can be shortened, the production of other substances can be avoided, and the utilization rate of raw materials can be improved. In the case of most catalysts in the same crystal phase, the larger the specific surface, the better. [0003] In relevant domestic patent documents, the Chinese patent application number 90105317.1 proposes a method for producing β-type aluminu...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C01F7/14
Inventor 张蕾王世全栾福森孙丽菊颜廷厚王剑许智芳
Owner GUIZHOU BRANCH CHINA ALUMINUM IND
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