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Prepn process of multilayer porous active compound TiO2 photocatalyst

A photocatalyst and active technology, which is applied in the direction of catalyst activation/preparation, chemical instruments and methods, physical/chemical process catalysts, etc. It can solve the problems of weak carrier binding, activity and application range, and the impact of repeated use cycles.

Inactive Publication Date: 2007-05-23
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the improvement of these technologies is still unsatisfactory. Whether the nano-photocatalytic particles are bonded or deposited, they are not firmly combined with the carrier, and the activity, application range and repeated use cycle are all affected.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0030] Preparation of Multilayer Porous Active Composite TiO Using Activated Carbon Particles as Support 2 Photocatalyst, its method step is:

[0031] 1. Take 2000 grams of activated carbon and put it into deionized water, heat it at 60-100 ° C for 10 hours, filter the water, and dry it in vacuum for later use;

[0032] 2. Take 2000ml of analytically pure absolute ethanol, add 50ml of glacial acetic acid, add 30ml of analytically pure nitric acid, add 1 g of polyethylene glycol with a molecular weight of 2000, add 1 g of silver nitrate, stir and disperse for 3 hours, add analytically pure butyl titanate 500ml, blended evenly to obtain a sol, divided into 4 equal amounts of sol for later use;

[0033] 3. Take 1 part of the sol obtained in step 2, add 15ml of deionized water and stir evenly for 5 minutes, add the clean and dried activated carbon particle carrier material in step 1, stir evenly, place it for 3 hours, and place it in an alumina ceramic crucible. Put it in a hous...

Embodiment 2

[0039] Preparation of Multilayer Porous Active Composite TiO Using Non-porous Metal Stainless Steel Mesh as Support 2 Photocatalyst, its preparation steps are:

[0040] 1. Take stainless steel mesh (60 mesh) reel 2m 2 , degreasing and decontaminating treatment according to the metal cleaning process, dry for later use; take 20 grams of soluble starch and add 80 ml of deionized water, stir well, then add 400 ml of deionized water, heat at 100 ° C to boil and gelatinize, and obtain 500 ml of gelatinization solution, cool After standby; take 100ml of analytically pure sulfuric acid and add 1900ml of deionized water to prepare 2000ml of sulfuric acid diluent for subsequent use;

[0041] 2. Take 1000ml of analytically pure absolute ethanol, add 50ml of glacial acetic acid, add 30ml of analytically pure nitric acid, add 1 g of polyethylene glycol with a molecular weight of 2000, add 1 g of cerium nitrate, stir and disperse for 3 hours, add analytically pure butyl titanate 500ml, a...

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PUM

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Abstract

The present invention provides the preparation process of multilayer porous active composite TiO2 photocatalyst. Composite TiO2 sol with added gelatinized starch as carbon precursor and pore creating agent polyglycol RE ion or noble metal ion is first prepared through chemical sol process, and then loaded onto metal or non-metal carrier, active carbon carrier or carbon fiber carrier in several layers through microwave sintering or conventional sintering and superstrong solid acid modification, so as to prepare the multilayer porous active composite TiO2 photocatalyst. The composite TiO2 photocatalyst has adsorption, high photocatalytic activity, high water resistance and high airflow erosion resistance, and may be used in photocatalytic solid air purifying equipment for long term use in excellent performance.

Description

technical field [0001] The invention relates to an active composite TiO 2 Photocatalyst film preparation technology, especially on the surface of activated carbon, carbon fiber, porous metal and non-metal, and non-porous metal and non-metal support, preparing multi-layer porous active composite TiO with activated carbon adsorption properties 2 photocatalyst thin film method. Background technique [0002] Studies have shown that using TiO 2 Photocatalytic oxidation treatment of pollutants and organic components in the air has great potential application value. However, commonly processed TiO 2 The recombination rate of photogenerated electron-hole pairs of nanoparticles is high, resulting in low activity of the applied photocatalyst. At the same time, nanoparticles are small in size, and it is difficult to recycle and reuse them in practical applications. All of these hinder the application and popularization of photocatalytic materials. [0003] TiO 2 Nanoparticles of...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): B01J21/06B01J35/10B01J37/00
Inventor 董学斌董学军木士春陶剑青干维国刘启文董毅熊威董胜其
Owner WUHAN UNIV OF TECH