Supercharge Your Innovation With Domain-Expert AI Agents!

Compound with intramolecule change transfer and its preparing process

A technology for charge transfer and compounds, applied in the field of compounds with intramolecular charge transfer and their preparation

Inactive Publication Date: 2002-09-18
EAST CHINA UNIV OF SCI & TECH
View PDF0 Cites 3 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, metal phthalocyanines assembled from alkoxy groups and substituted tetrathiafulvalene monomers have not been reported.

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

preparation example Construction

[0017] The preparation method of the compound described in the present invention is described further below: (1) 2-(4,5-di-n-hexylthio-1,3-dithio-2-ylidene)-5-hydroxymethylene-5 - Preparation of hydrogen-6-dihydro-1,3-dithio[4,5-b][1,4]dithiocyclohexane:

[0018] After Zincate is dissolved in acetone, add hexyl bromide dissolved in acetone dropwise in boiling state, wherein the molar ratio of Zincate and hexyl bromide is 1:5.3, continue to reflux for 2-4 hours, and remove insoluble matter by suction filtration. The solvent was distilled off, and the residue was purified by column chromatography to obtain 4,5-di-n-hexylthio-1,3-dithiol-2-thione, one of the raw materials required for the coupling reaction. The reaction formula is as follows: Show:

[0019] After reflux for 20 hours in the same way, another raw material 5,6-dihydro-5-acetoxymethylene-1,3-dithio[4,5-b][1,4] was purified to obtain the coupling reaction Dithiocyclohexane-2-thione.

[0020] In order to improve...

Embodiment 4

[0026] Example 4, 5-di-n-hexylthio-1,3-dithiole-2-thione

[0027] 8g Zincate (11.2mmol) was dissolved in 100mL acetone, heated to reflux with stirring, 50mL acetone solution containing 9.4mL (60mmol) bromohexane was added dropwise, and refluxed for 4 hours. Suction filtration to remove insoluble matter. Acetone was removed by rotary evaporation. The residue was subjected to column chromatography (chloroform:petroleum ether=1:2 as the developing solvent) and the developing solvent was rotated to obtain 8 g of orange-red oil with a yield of 98%. MS(EI): m / z(%)=367(M + +1, 14.119), 366 (M + , 27.196) 5,6-dihydro-5-acetoxymethylene-1,3-dithio[4,5-b][1,4]dithiocyclohexane-2-thione

[0028] Add 7.2g (10mmol) Zincate and 100mL acetone into a 250mL three-neck flask. 11.4 mL (80 mmol) 2,3-dibromopropyl acetate / 50 mL acetone were added dropwise under stirring and reflux, and the reaction was carried out for about 20 hours. TLC tracking, the developing solvent...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

PUM

No PUM Login to View More

Abstract

The present invention discloses the structure and preparing process of a molecular assembly of metal phthalocyamine and substituted dithioethylene tetrathiofulvalene. The said molecular assembly is amacro-molecular compound with intramolecule charge transfer, and can be used in molecule switch field.

Description

technical field [0001] The invention relates to a compound with intramolecular charge transfer and a preparation method thereof. Background technique [0002] Tetrathiafulvalene (TTF) and its derivatives are good π-electron donors (Donor), which can generate stable cationic radicals. This free radical can generate conductive intermolecular charge transfer complexes with numerous electron acceptors, for example, the CT-complex of tetrathiofulvalene and tetracyanoquinodimethane (TTF-TCNQ ) have metallic conductivity at room temperature. At the same time, tetrathiafulvalene and its derivatives are good molecular assembly materials, which can be matched with other functional material molecules to form intramolecular CT-complexes. This intramolecular charge transfer complex has multiple electrical, optical, and magnetic activities, and can be used as a molecular electronic device material for VLSI or as a "molecular switch" for future photonic computers, ...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to View More

Application Information

Patent Timeline
no application Login to View More
IPC IPC(8): C07D519/00
Inventor 沈永嘉胡莹玉许煦
Owner EAST CHINA UNIV OF SCI & TECH
Features
  • R&D
  • Intellectual Property
  • Life Sciences
  • Materials
  • Tech Scout
Why Patsnap Eureka
  • Unparalleled Data Quality
  • Higher Quality Content
  • 60% Fewer Hallucinations
Social media
Patsnap Eureka Blog
Learn More

Browse by: Latest US Patents, China's latest patents, Technical Efficacy Thesaurus, Application Domain, Technology Topic, Popular Technical Reports.

© 2025 PatSnap. All rights reserved.Legal|Privacy policy|Modern Slavery Act Transparency Statement|Sitemap|About US| Contact US: help@patsnap.com