The present application relates to the field of photoelectric technology, especially to organic light-emitting material, organic electroluminescent device and preparation thereof. The organic light-emitting material based on acephenanthrylene derivative and the organic electroluminescent device thereof, the material is fused through
benzene ring, ensures that the
excited state has high oscillator strength, is conducive to
radiation transition, and the rigid fused ring structure can effectively inhibit intramolecular vibration, helps to inhibit the non-
radiative transition behavior of the
excited state and obtain high
photoluminescence efficiency, in addition, the molecule can form
intermolecular charge transfer aggregate to reduce the non-adiabatic
coupling of electrons, so as to realize low non-
radiative transition rate, further improve the
photoluminescence efficiency, and also can stabilize the
excited state energy, can be further applied to organic electroluminescent device, realizes high
electroluminescence efficiency.