Positive electrode material of alkaline battery and its preparation method

A cathode material, alkaline battery technology, applied in the direction of alkaline storage battery electrodes, alkaline storage batteries, electrode manufacturing, etc., can solve the problems of unsatisfactory storage performance of alkaline batteries, long production process routes, unsatisfactory storage performance, etc. Excellent high-load discharge characteristics and durability, the effect of solving self-discharge and large discharge current

Inactive Publication Date: 2003-03-26
CHANGSHUN CHEM JIANGMEN CITY
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Problems solved by technology

[0002] With the popularization and popularization of a series of small portable electronic devices such as digital cameras, digital video cameras and electric toys, the demand for power batteries used in these electronic devices is also increasing, and with the continuous improvement and development of these electronic devices, their demand for The requirements of the battery are getting higher and higher. When the battery is working under a heavy load, it is required to have a high working voltage and a large working current, as well as excellent durability. Even after being stored at a high temperature, it can ideally maintain the above excellent characteristics. Alkaline manganese batteries, which have been widely used in the past, have obvious deficiencies in the discharge of the above-mentioned electronic equipment under heavy loads. This is mainly because the manganese dioxide used as the positive electrode material in alkaline manganese batteries is a simple solid phase Chemical reaction discharge, the discharge voltage is low, the current is small, it is difficult to meet the requirements of

Method used

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  • Positive electrode material of alkaline battery and its preparation method
  • Positive electrode material of alkaline battery and its preparation method
  • Positive electrode material of alkaline battery and its preparation method

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Embodiment Construction

[0015] A positive electrode material for alkaline batteries, the positive electrode material is a kind of β-nickel zinc oxyhydroxide containing nickel and zinc hydroxides in the form of eutectic on the crystal lattice, and has the following molecular formula: β-Ni (1-X) Zn X O (1-X) (OH) (1+X) , Where the number of moles of X is greater than or equal to 2% but less than or equal to 20%, due to the introduction of zinc-containing hydroxide, on the crystal lattice of β-nickel oxyhydroxide, it will increase the oxygen reaction of β-nickel oxyhydroxide The oxygen overpotential can satisfactorily inhibit or greatly slow down the oxygen evolution reaction of β-nickel oxyhydroxide, and better solve the self-discharge defect of β-nickel oxyhydroxide. Therefore, one of the alkaline batteries involved in the present invention is used. The positive electrode material β-nickel zinc oxyhydroxide is the positive electrode, zinc is the negative electrode, and the concentrated alkali solution is ...

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Abstract

The invention discloses Beta-hydroxyl zinc-nickel oxide crystal, which is of hydrated oxide of nickel and zinc existed in eutectic form, and its preparing method. Comparing with prior art, the alkaline battery prepared by use of the said crystal as the material of the positive electrode, zinc as the negative electrode, the concentrated alkali solution as the electrolytic solution. The alkali battery provides higher discharge voltage and larger discharge current. With being even stored in high temperature, the battery still keeps excellent large load discharge characteristic and durability. Possessing the features of short preparation technological flow and simple operation, the invention is suitable for being as the material of the positive electrode of the alkali battery.

Description

Technical field [0001] The invention relates to a positive electrode material of an alkaline battery and a preparation method thereof. Background technique [0002] With the popularization and promotion of a series of small portable electronic devices of digital cameras, digital video cameras and electric toys, the demand for power batteries used by these electronic devices is also increasing, and as these electronic devices continue to improve and develop, they are The requirements for batteries are getting higher and higher. They are required to have high working voltage, high working current, and excellent durability when working under heavy loads. Even after storage at high temperatures, they can also ideally maintain the above-mentioned excellent characteristics. Alkaline manganese batteries that have been widely used in the past have obvious deficiencies when the above-mentioned electronic equipment requires heavy load to discharge. This is mainly because...

Claims

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Application Information

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IPC IPC(8): C01G53/02C01G53/04H01M4/32H01M4/36H01M10/24
CPCY02E60/124H01M2004/028H01M10/24H01M4/48H01M4/32Y02E60/10
Inventor 田吉平马柱坚郭少斌周宇海
Owner CHANGSHUN CHEM JIANGMEN CITY
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