The invention discloses a flameproof lithium battery starting power source for coal mine. The flameproof lithium battery starting power source comprises a power supply circuit, a power management circuit, a control room circuit, a charge-discharge protection circuit, a charging circuit and a starting circuit. A lithium battery management unit is arranged in the power management circuit; an intermediate relay and a direct-current contactor are arranged in the charge-discharge protection circuit; the lithium battery management unit is capable of realizing detection and warning on the voltage, the temperature and the current of an individual battery; when the charging of a lithium battery pack is finished, the lithium battery management unit automatically controls the intermediate relay to switch off, and consequently, direct-current contact is stopped and the charging of the lithium battery pack is ended; in case of abnormal use of the lithium battery pack, the lithium battery management unit controls the intermediate relay to switch off, and consequently, the direct-current contact is stopped and the charging and discharging of the lithium battery pack are ended, and therefore, the lithium battery pack can be protected. In addition, the lithium battery management unit can be powered by a charger by use of a first diode and a second diode when the lithium battery pack is completely drained.