Plastic optical fiber with fluorizated packet-layer and its prepn. method

A technology of a plastic optical fiber and a manufacturing method, which is applied in the field of fluorinated clad plastic optical fiber and its manufacturing, can solve the problems of high price, increased optical fiber loss, and high equipment requirements, so as to prevent light leakage, save equipment investment, and control fluorine degree of effect

Inactive Publication Date: 2003-05-07
SICHUAN HUIYUAN PLASTIC OPTICAL FIBER
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The first method has complex production process and high equipment requirements; in the co-extrusion process, the extrusion processing temperature of the core layer and the cladding material needs to be similar, and at the same time, it is easy to contaminate the optical fiber material and generate bubbles, interface defects, etc., resulting in increased optical fiber loss. Large; especially high-transparency fluororesin with similar processing temperature to PMMA has few varieties and high price, which limits the popularization and use of plastic optical fiber
The second method, although the production process is simple, is more likely to contaminate the fiber material and generate bubbles, interface defects, etc., resulting in increased fiber loss, making it difficult to manufacture low-loss fibers

Method used

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  • Plastic optical fiber with fluorizated packet-layer and its prepn. method
  • Plastic optical fiber with fluorizated packet-layer and its prepn. method
  • Plastic optical fiber with fluorizated packet-layer and its prepn. method

Examples

Experimental program
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Effect test

Embodiment 1

[0033] figure 1 A structural schematic diagram of the multimode step plastic optical fiber (SIPOF) of the present invention is given. see figure 1 , there is a fluoride cladding 2 on the outer periphery of the core 1.

Embodiment 2

[0035] figure 2 A schematic structural view of the multimode gradient plastic optical fiber (GIPOF) of the present invention is given. see figure 2 , there is a fluoride cladding 4 on the periphery of the core 3 .

Embodiment 3

[0037] Purify methyl methacrylate by distillation under reduced pressure, then add the purified initiator and chain transfer agent, under the protection of high-purity nitrogen with a purity greater than 99.9%, polymerize at 40-80°C for 5-48h, and then extrude extruding, pulling, and cooling to obtain a polymerized high-purity polymethylmethacrylate (PMMA) core material, and melt extruding fibers with a diameter of 1 mm through the extruder. This fiber is put into the fluorination furnace that contains 10% volume ratio (1 standard atmospheric pressure) fluorination agent, carries out fluorination reaction certain hour (0 # Sample fluorination 0h, 2 # The sample was fluorinated for 2h, 4 # The sample was fluorinated for 3h, 5 # Sample fluorination 4h). The relationship between the surface F / C atomic ratio and the fluorination time is analyzed by electron spectroscopy. Figure 4 . It can be seen that the degree of fluorination increases with the prolongation of fluorination...

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Abstract

This invention provides a fluorate clad plastic fiber characterizing in having fluorate clad a fibre core or plastic fiber. This invention also provides the process method for fluorate clad plastic fiber including preparing materials: preparing fibre core or plastic fibre; putting fibre core or plastic fibre into a fluorate over with the concentration of 0.01%-10% to perform fluorate reaction for 2-72h at 10-80 deg.c to finish the fluorate clad plastic fiber.

Description

Technical field: [0001] The invention belongs to the field of multimedia information transmission materials for information communication and the field of advertising lighting, and relates to a novel plastic optical fiber product and a manufacturing method thereof that form a cladding through direct fluorination of the surface. Background technique: [0002] Plastic optical fiber (POF), also known as polymer optical fiber and polymer optical fiber, is composed of a transparent polymer core with a high refractive index and a transparent polymer cladding with a low refractive index. There are mainly step type (SI POF) and Gradient plastic optical fiber (GI POF), such as figure 1 , figure 2 . Due to the advantages of large diameter, good flexibility, low density, low loss window in the visible light region, and low cost and processing costs, plastic optical fiber has gradually been widely used in the fields of lighting, decoration, sensors, local area networks, and automotiv...

Claims

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Application Information

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Patent Type & Authority Applications(China)
Inventor 储九荣吴祥君温序铭张海龙刘志飞
Owner SICHUAN HUIYUAN PLASTIC OPTICAL FIBER
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