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Synthetic method for anode material of lithium ion cell

A technology for lithium ion batteries and positive electrode materials, which is applied in battery electrodes, electrode manufacturing, lithium compounds, etc., can solve the problems of environmental pollution, environmental pollution, waste of water resources, etc., and achieves water saving, cost reduction, and elimination of washing steps. Effect

Inactive Publication Date: 2005-06-01
RIZHAO HUAXUAN NEW ENERGY
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

Generally speaking, the synthesis of positive electrode materials needs to add sodium hydroxide solution to the soluble salt solution to react to form precipitates, which often have harmful metal sodium ions attached to them. In order to remove these metal ions, it will take more than three times. Washing with water to remove useless metal ions, these lotions are generally discharged into the environment, causing pollution to the environment
It wastes water resources and pollutes the environment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0012] Embodiment 1: first dissolve cobalt nitrate and lithium hydroxide in water respectively at room temperature, and uniformly mix and react with lithium hydroxide solution and ammonia solution and cobalt nitrate solution, the add-on guarantees Li: Co=1: 1, and the ammonia add-on is Ensure that cobalt ions exist in the form of hydroxide; until the complete reaction does not continue to generate cobalt hydroxide precipitate; dry the cobalt hydroxide precipitate and lithium nitrate solution generated by the reaction at a constant temperature of 200 °C to remove moisture, and keep it at a constant temperature of 900 °C. After firing for 3 hours, lithium cobalt oxide was synthesized.

[0013] The molecular formula of lithium cobaltate is: LiCoO 2

Embodiment 2

[0014] Example 2: At 50°C, first dissolve the mixture of cobalt nitrate, manganese nitrate and nickel nitrate (where Co:Mn:Ni=1:1:1) and lithium hydroxide in water, respectively, dissolve the lithium hydroxide solution and The ammonia solution and the mixture solution are uniformly mixed and reacted, and the addition amount ensures that Li:M=1.02:1 (M represents cobalt, nickel and manganese mixed metal ions), and the addition amount of ammonia water is to ensure that cobalt ions, nickel ions, and manganese ions exist in the form of hydroxides , until the complete reaction does not continue to generate hydroxide precipitation, the hydroxide precipitation and the aqueous solution of lithium nitrate generated by the reaction are removed by spray drying to remove moisture, and calcined at a constant temperature of 900 ° C for 5 hours to synthesize manganese cobalt lithium nickelate .

[0015] The molecular formula of manganese cobalt lithium nickelate is: Li 1.02 Co 0.33 Mn 0.3...

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PUM

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Abstract

The process of synthesizing positive electrode material for lithium ion cell includes the following steps: adding lithium hydroxide solution and ammonia water solution homogeneously into soluble salt solution to generate hydroxide precipitate and lithium salt solution, with the added lithium hydroxide solution amount being so that the ratio between other metal ion and lithium ion in the solution is 1 to 0.9-1.2 and the added ammonia water being so as to ensure the metal ion in the salt existing in hydroxide form; eliminating water from the reaction product; and backing at constant temperature within 700-950 deg.c for certain time to synthesize the positive electrode material for lithium ion cell of molecular expression of Li1+xMO2, with x having the range of -0.1 to +0.2. The present invention uses lithium hydroxide, rather than sodium hydroxide, and there is no need of water washing to eliminate lithium ion attached to the precipitate, resulting in saving in water and lowered cost.

Description

technical field [0001] The present invention relates to a method for synthesizing a positive electrode material for a lithium ion battery. Background technique [0002] As a green high-energy power source, lithium ion has been widely valued for more than ten years. It has the characteristics of high energy, good cyclability and low self-discharge. In order to give full play to the performance characteristics of lithium-ion batteries, researchers around the world conduct active research on lithium-ion batteries. Generally speaking, the synthesis of cathode materials requires adding sodium hydroxide solution to the soluble salt solution to react to form a precipitate. The precipitate is often accompanied by harmful metal sodium ions. In order to remove these metal ions, it takes more than three times. Washing with water to remove useless metal ions, these washings are generally discharged into the environment, causing pollution to the environment. It wastes water resources a...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C01D15/00C01G1/02C01G45/00C01G51/00C01G53/00H01M4/04H01M4/48H01M4/50H01M4/52H01M4/58H01M10/36
CPCH01M4/505H01M4/525H01M10/0525Y02E60/10
Inventor 谷亦杰
Owner RIZHAO HUAXUAN NEW ENERGY
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