Composite particles for electrode use and producing method thereof, electrode and manufacturing method thereof and electrochemical device and producing method thereof
A technology of composite particles and particles, applied in electrode manufacturing, electrical components, electrochemical generators, etc.
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Embodiment 1
[0213] (1) Preparation of composite particles
[0214] First, composite particles usable for forming an active material-containing layer of a cathode of a lithium ion secondary battery were produced by the method described above through the granulation step described below by the procedure shown below. Here, the composite particles P10 consist of a cathode electrode active material (24% by mass of large-diameter particles and 56% by mass of small-diameter particles), a conductive additive (8% by mass), and a binder (12% by mass).
[0215] As the electrode active material of the cathode, lithium manganese oxide (LiMn 2 o 4 ) composed of large diameter particles (average particle diameter R: 12μm, BET specific surface area: 0.5m 2 / g) and small-diameter particles made of lithium manganate (average particle size r: 0.4μm, BET specific surface area: 12m 2 / g). In addition, acetylene black was used as a conductive auxiliary agent. As the binder, polyvinylidene fluoride was use...
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