Method of preparing polyparaphenyl bracing benzdioxazole fibre
A technology of benzobisoxazole and polyparaphenylene, which is applied in the field of preparation of polyparaphenylenebenzobisoxazole fiber, can solve the problems of long reaction time, high recycling cost, high equipment requirements, etc. The Effect of Concentrated Logarithmic Viscosity
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Embodiment 1
[0019] With reference to accompanying drawing 1, 4,6-diaminoresorcinol-terephthalate, polyphosphoric acid and P 2 o 5 According to the weight ratio of 1: 1.5: 0.7 into the pre-condensation reactor, stirred at 80 ° C for 2 hours, then heated to 150 ° C within 3 hours and reacted for 5 hours, and then heated to 180 ° C for 2 hours to obtain The PBO slurry enters the twin-screw reaction extruder with 25mm, length-to-diameter ratio of 40, rotating speed of 15 rpm, and temperature of 180°C. The temperature of the spinneret is 170°C, the size of the spinneret is 0.2×60 holes, and it passes through a tunnel with a length of 1.5 meters and a temperature of 70°C. The atmosphere in the tunnel contains H 3 PO 4 0.08g / L, side blowing speed 0.1 m / s, spinning speed 150 m / min, nozzle stretching 15 times, the obtained PBO fiber tow immediately enters the coagulation bath containing 5% phosphoric acid and the temperature is 40 ℃, After leaving the coagulation bath, the tow is dissolved in...
Embodiment 2
[0021] 4,6-diaminoresorcinol-terephthalate, polyphosphoric acid and P 2 o 5 According to the weight ratio of 1:4:2, put it into the pre-condensation reactor, stir at 90°C for 2 hours, then raise the temperature to 160°C within 3 hours and react for 5 hours, then raise the temperature to 180°C for 2 hours, and the obtained PBO slurry enters 50mm, length-to-diameter ratio of 50, rotating speed of 150 rpm, temperature of 180°C twin-screw reaction extruder continues to react, after being filtered, it enters the metering pump and is sent to the spinneret, and the spinning temperature is 180°C , the size of the spinneret is 0.2×60 holes, passing through a tunnel with a length of 3.0 meters and a temperature of 75°C, the atmosphere in the tunnel contains H 3 PO 4 0.1g / L, side blowing speed 0.3 m / s, spinning speed 150 m / min, nozzle stretching 25 times, the obtained PBO fiber tow immediately enters the coagulation bath containing 15% phosphoric acid and the temperature is 25 ℃, Af...
Embodiment 3
[0023] 4,6-diaminoresorcinol-terephthalate, polyphosphoric acid and P 2 o 5 According to the weight ratio of 1:6:3, add it into the pre-condensation reactor, stir at 80°C for 2 hours, then raise the temperature to 150°C within 3 hours and react for 5 hours, then raise the temperature to 180°C and react for 2 hours, the obtained PBO The slurry enters the twin-screw reaction extruder with 105mm, length-diameter ratio of 60, rotating speed of 200 rpm, and temperature of 190°C. ℃, the size of the spinneret is 0.23×100 holes, passing through a tunnel with a length of 3.5 meters and a temperature of 80°C, the atmosphere in the tunnel contains H 3 PO 4 0.12g / L, side blowing speed 0.5 m / s, spinning speed 150 m / min, nozzle stretched 30 times, the obtained PBO fiber tow immediately enters the coagulation bath containing 25% phosphoric acid and the temperature is 40 ℃, After leaving the coagulation bath, the tow is dissolved in 10 g / L NH 3 After soaking in 8 g / L potassium hydroxide...
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