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Composite flocculation agent of modified rectorite with polysaccharase

A compound flocculant and polysaccharide compounding technology, which is applied in the direction of flocculation/sedimentation water/sewage treatment, etc., can solve the problems of limited adsorption performance and effect, and achieve the effect of reducing the cost of chemicals

Inactive Publication Date: 2006-01-25
WUHAN UNIV OF TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0002] As a cheap and easy-to-obtain mineral material, rectorite has been widely studied and applied in the field of water treatment, but only a single natural rectorite is used to directly treat wastewater, and its adsorption performance and effect are very limited. of

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0016] 10 grams of sodium carbonate and 0.5 gram of sodium polyphosphate are added to 440 grams of hydrated pulpy natural rectorite slurry, and the mass ratio of natural rectorite and water in the slurry is 2:8. The mass content of rectorite is 70%, the fineness is ≤325 mesh, and the specific surface area is 260m 2 / g, density 2.77g / cm 3 , after stirring evenly, put it into a ceramic ball mill for rolling for 3 hours, take out and seal and age for 24 hours to obtain a sodium rectorite slurry for subsequent use; then sodium hydroxide and aluminum chloride are prepared into 1wt% and 2wt% respectively Aqueous solution, and then according to the mass ratio of 1wt% sodium hydroxide aqueous solution: 2wt% aluminum trichloride aqueous solution = 1: 100, mix the two evenly, stir at 70 ° C for 3 hours, and then seal and age for 24 hours to obtain aluminum crosslinked agent for later use; finally, mix the above-prepared aluminum crosslinking agent with the sodium rectorite slurry at a ...

Embodiment 2

[0020] 10 grams of sodium carbonate and 0.5 gram of sodium polyphosphate are added to 460 grams of hydrated pulpy natural rectorite slurry, the mass ratio of natural rectorite and water in the slurry is 2:8, the natural rectorite The mass content of rectorite is 70%, the fineness is ≤325 mesh, and the specific surface area is 260m 2 / g, density 2.77g / cm 3 , after stirring evenly, put it into a ceramic ball mill for rolling for 3 hours, take out and seal and age for 24 hours to obtain a sodium rectorite slurry for subsequent use; then sodium hydroxide and aluminum chloride are prepared into 1wt% and 2wt% respectively Aqueous solution, and then according to the mass ratio of 1wt% sodium hydroxide aqueous solution: 2wt% aluminum trichloride aqueous solution = 1: 100, mix the two evenly, stir at 70 ° C for 3 hours, and then seal and age for 24 hours to obtain aluminum crosslinked agent for later use; finally, mix the above-prepared aluminum crosslinking agent with the sodium rect...

Embodiment 3

[0024] Prepare modified rectorite and natural organic polymer polysaccharide according to the method of embodiment 2, take by weighing 98.8 grams of modified rectorite prepared and 1.2 grams of natural organic polymer polysaccharide, and join in the solid powder ball mill and grind and disperse, through After dispersing and grinding for 30 minutes, the powder fineness is ≤325 mesh, and the finished product of modified rectorite and polysaccharide composite flocculant is obtained.

[0025] Compared with the treatment of printing and dyeing wastewater with this flocculant and a single natural rectorite flocculant, the removal rate of organic pollutants (COD) in water by this flocculant has increased by 12-18%, and the removal rate of suspended solids (SS) in water has increased 16-22%, and the drug cost has dropped by 6-10%. The specific comparison results are shown in Table 1-Table 3.

[0026]

[0027]

[0028]

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Abstract

A composite flocculant for treating sewage is composed of modified rectorite (97.5-98.8 mass%) and polyose (1.2-2.5). It is prepared through modifying the natural rectorite by sodium carbonate and AlCl3, and proportionally mixing it with water-soluble organic high-molecular polyose. Said polyose is extracted from the shell of red lobster. Its advantages are high flocculating effect and low cost.

Description

Technical field: [0001] The invention relates to a method of modifying natural rectorite with sodium carbonate and aluminum trichloride, and compounding the modified rectorite with water-soluble organic polymer polysaccharide to prepare modified rectorite and Formula and process of polysaccharide composite flocculant. Background technique: [0002] As a cheap and easy-to-obtain mineral material, rectorite has been widely studied and applied in the field of water treatment, but only a single natural rectorite is used to directly treat wastewater, and its adsorption performance and effect are very limited. of. Therefore, the natural rectorite is modified, and the modified rectorite is compounded with water-soluble organic polymer polysaccharides to form a composite flocculant to improve its removal rate of organic pollutants in water and suspended solids in water. The removal rate has significant economic and environmental benefits. Invention content: [0003] The purpose...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C02F1/52C02F1/56
Inventor 曾德芳袁继祖
Owner WUHAN UNIV OF TECH