Process for producing cyclohexanone oxime

A technology of cyclohexanone oxime and cyclohexanone, which is applied in oxime preparation, organic chemistry and other directions, can solve the problems of reduced cyclohexanone oxime selectivity, reduced cyclohexanone conversion rate, etc., and achieves the effect of excellent long-term productivity

Active Publication Date: 2006-06-28
SUMITOMO CHEM CO LTD
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Problems solved by technology

[0003] However, in the above-mentioned ammoximation reaction, since the titanium silicate catalyst gradually deteriorates with the reaction time, the conversion rate of cyclohexanone decreases and the selectivity of cyclohexanone oxime decreases.

Method used

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Examples

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Embodiment 1

[0030] Using an autoclave with a capacity of 1 liter as a reaction vessel, 3 g of catalyst and 500 g of hydrous tert-butanol (13% by weight of water) were added thereto, stirred, and kept at a temperature of 85° C. and a pressure of 0.25 MPa (gauge pressure). Then, 67 g / hour of cyclohexanone, 280 g / hour of aqueous tert-butanol (12% by weight of water) solution with an ammonia concentration of 8 to 9% by weight, and 45 g / hour of 60% by weight hydrogen peroxide were started to be supplied therein at the following speeds, and The liquid phase of the reaction mixture was initially taken out through the filter so that the volume of the reaction mixture in the reactor was maintained at 500 ml, thereby starting the continuous reaction at a temperature of 85° C. and a pressure of 0.25 MPa (gauge pressure). After the reaction started, the reaction was continued under the same conditions. Helium was introduced into the reactor at a flow rate of 5 L / hour, and the waste gas was discharged ...

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Abstract

The present invention can provide a method for preparing cyclohexanone with good long-term productivity while controlling the catalyst cost as much as possible, maintaining the conversion rate of cyclohexanone and the selectivity of cyclohexanone oxime in the ammoximation reaction of cyclohexanone hexanone oxime. Among them, when cyclohexanone, hydrogen peroxide, and ammonia are continuously reacted in the presence of a titanium silicate catalyst to prepare cyclohexanone oxime, a multi-stage operation condition including the following two operation stages is adopted, that is, by adding silicic acid The titanium catalyst is the first operation stage in which the concentration of the titanium silicate catalyst in the reaction mixture is increased, and the second operation stage in which the titanium silicate catalyst concentration in the reaction mixture is maintained within a predetermined range by taking out and adding the titanium silicate catalyst.

Description

technical field [0001] The invention relates to a method for preparing cyclohexanone oxime through the ammoximation reaction of cyclohexanone. Cyclohexanone oxime is useful as a raw material of ε-caprolactam and the like. Background technique [0002] As one of the preparation methods of cyclohexanone oxime, it is proposed to use hydrogen peroxide and ammonia to carry out the ammoximation reaction of cyclohexanone in the presence of a titanium silicate (titanosilicate) catalyst (for example, refer to Patent Documents 1 to 4 ). This method has the following advantages: it is not necessary to neutralize sulfuric acid with ammonia as in the conventional method of oximation using hydroxylamine sulfate, and since the reaction is a solid catalyst, the separation of the product and the catalyst is easy. [0003] However, in the above-mentioned ammoximation reaction, since the titanium silicate catalyst gradually deteriorates with the reaction time, the conversion rate of cyclohex...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C249/04C07C251/44
CPCC07C249/04C07C251/44C07C249/06C07C249/14
Inventor F·特里维隆P·弗兰老川幸
Owner SUMITOMO CHEM CO LTD
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