Polymerization reaction end gas recovering process

A polymerization reaction and tail gas technology, which is applied in the separation of dispersed particles, chemical instruments and methods, separation methods, etc., can solve the problems of waste of reaction raw materials, insufficient combustion, and unfavorable long-term development of the national economy. The effect of easy management of the recycling device

Active Publication Date: 2006-07-19
SINOPEC SICHUAN VINYLON FACTORY
View PDF0 Cites 12 Cited by
  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The method of high discharge is to use the chimney system to lead the tail gas to a space higher than the ground (30 meters, 50 meters, etc. according to needs) and discharge it directly. The high discharge gas does not pollute the environment relatively significantly, or in There will be no obvious environmental pollution in a short period of time, but it is not a proper method to directly discharge the tail gas of chemical production into the atmosphere. The pollution to the environment will gradually become apparent after decades, which is not conducive to the long-term development of the national economy and the Ecological Environment of the Earth
The method of incineration is to pass the intermittently produced tail gas through the flare system and ignite and burn it when it is discharged. It is suitable for some exhaust gas that is significantly polluted or slightly toxic but combustible, but when burning, due to the efficiency of the flare system, the design And other problems, resulting in insufficient combustion during combustion to produce a large amount of carbon monoxide, carbon black, etc., which directly pollute the atmosphere.
[0003] However, the tail gas produced by batch polymerization contains a large amount of polymerization reaction raw materials, and the content is often more than 80%. If the above-mentioned treatment method is adopted, it will not only cause environmental pollution, but also greatly waste the reaction raw materials

Method used

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
View more

Examples

Experimental program
Comparison scheme
Effect test

Embodiment

[0015] Embodiment: The present invention takes the recovery of high-temperature and high-pressure tail gas used in the ethylene-vinyl acetate production process in a batch polymerization device as an example to further illustrate the present invention, but it is not limited thereto.

[0016] A process for recovering the tail gas of a polymerization reaction, the key of which is: after the tail gas generated by the polymerization reaction is decompressed and washed with water, the high-temperature and high-pressure tail gas is converted into a low-temperature and low-pressure gas and temporarily stored in a gas cabinet, and then the low-temperature and low-pressure gas is extracted. The gas is washed and compressed, dried, and finally refined to obtain usable raw materials for polymerization. That is:

[0017] Decompression: After the polymerization reaction is over, control the pressure of the reactor at 1.8-2.0MPa, and the temperature at ≤70°C. Control the high-temperature an...

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

PUM

No PUM Login to view more

Abstract

The invention discloses a recovery technology of high temperature and high pressure tail gas in the interval polymeric device, which is characterized by the following: decompressing and rinsing the high temperature and high pressure tail gas; transmitting the gas into low temperature and low pressure gas in the gas cabinet; cleaning and compressing and drying the low temperature and low pressure gas; producing fine polymeric reaction material. The invention can recover the interval tail gas and reinforce the operational reliability, which protects the environment and saves energy.

Description

technical field [0001] The invention relates to a process for recovering tail gas of polymerization reaction, in particular to a process for recovering high-temperature and high-pressure tail gas produced by ethylene-vinyl acetate, vinyl chloride-vinyl acetate and other production processes in a batch polymerization device. Background technique [0002] In the existing technology, the treatment methods of intermittently produced tail gas are generally high emission and incineration. The method of high discharge is to use the chimney system to lead the tail gas to a space higher than the ground (30 meters, 50 meters, etc. according to needs) and discharge it directly. The high discharge gas does not pollute the environment relatively significantly, or in There will be no obvious environmental pollution in a short period of time, but it is not a proper method to directly discharge the tail gas of chemical production into the atmosphere. The pollution to the environment will gr...

Claims

the structure of the environmentally friendly knitted fabric provided by the present invention; figure 2 Flow chart of the yarn wrapping machine for environmentally friendly knitted fabrics and storage devices; image 3 Is the parameter map of the yarn covering machine
Login to view more

Application Information

Patent Timeline
no application Login to view more
Patent Type & Authority Applications(China)
IPC IPC(8): B01D53/00
Inventor 董泽明谢卫东宁威叶勇李华苏蒋晓
Owner SINOPEC SICHUAN VINYLON FACTORY
Who we serve
  • R&D Engineer
  • R&D Manager
  • IP Professional
Why Eureka
  • Industry Leading Data Capabilities
  • Powerful AI technology
  • Patent DNA Extraction
Social media
Try Eureka
PatSnap group products