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Macropore hydrogenation catalyst and its preparation method

A hydrogenation catalyst and catalyst technology, which are applied in the directions of catalyst activation/preparation, catalyst support, chemical instruments and methods, etc., can solve the problems of limited actual range and uncertain characterization of catalyst pore opening, and achieve the effect of improving catalytic activity.

Inactive Publication Date: 2006-09-13
CHINA UNIV OF PETROLEUM (BEIJING)
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Therefore, in the prior art, for the same composition, the actual range of adjustment of the pore structure parameters of catalysts prepared by the same method is quite limited
In addition, the openness of the pores is also an important indicator to determine whether the catalyst has good diffusion performance. However, the characterization of the openness of the catalyst pores has always been uncertain in the prior art.

Method used

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  • Macropore hydrogenation catalyst and its preparation method
  • Macropore hydrogenation catalyst and its preparation method
  • Macropore hydrogenation catalyst and its preparation method

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0033] Embodiment 1, one of the synthesis of nano / submicron polystyrene particle template

[0034] Get 0.2605 grams of sodium styrene sulfonate, 0.431 grams of sodium bicarbonate, 125 milliliters of styrene and 875 milliliters of water into the reactor with stirring, and stir while heating to make the temperature of the reactor rise to about 75 ° C. After the temperature of the reactant stabilized, 0.4985 g of potassium peroxodisulfate was added to initiate the polymerization reaction. It can be seen that the reaction solution first changes from colorless to protein-colored, and finally turns milky white. The polymerization reaction was carried out at 75° C. under stirring for 8 hours to obtain a monodisperse polystyrene emulsion. The particle diameter of the polystyrene colloidal particles measured by a Zetasizer Nano-ZS dynamic light scattering particle size analyzer of Malvern Instrument Co., Ltd. is 345 nm. Its particle diameter measured by transmission electron microsco...

Embodiment 2

[0037] Embodiment 2, the second synthesis of nano / submicron polystyrene particle template

[0038] Get 2.851 grams of sodium lauryl sulfate, 1.63 grams of n-amyl alcohol, 100 milliliters of styrene and 840 milliliters of water into the reactor with stirring; the temperature of the reactor is raised to about 83° C. while heating. After the temperature of the reactant stabilized, 0.80 g of potassium peroxodisulfate was added to initiate the reaction. The reaction solution slowly changes from colorless to protein or milky white. The reaction was carried out at 83° C. under stirring for 3 hours to obtain a monodisperse polystyrene emulsion. The average particle diameter of the polystyrene colloidal particles measured by a Zetasizer Nano-ZS dynamic light scattering particle size analyzer of Malvern Instrument Co., Ltd. is 63.8 nanometers.

[0039] By changing the amount of reagents, polystyrene template particles with different particle sizes can be synthesized. Some experimenta...

Embodiment 3

[0041] Embodiment 3, the synthesis of nanometer polystyrene / polymethyl methacrylate composite particles

[0042] Add 7 grams of sodium lauryl sulfate, 0.8 grams of ammonium persulfate and 840 milliliters of water into the reactor, stir and heat up to 80 degrees Celsius. Add 40 ml of methyl methacrylate and finally 90 ml of styrene dropwise. A protein-colored product was obtained after 90 minutes of reaction. The average particle diameter of the polystyrene / polymethyl methacrylate composite particles measured by a Zetasizer Nano-ZS dynamic light scattering particle size analyzer of Malvern Instrument Co., Ltd. is 24.2 nm.

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Abstract

A macroreticular hydrocatalyst for the catalytic hydrogenation of heavy oil is prepared through providing organic particles as template agent, compounding it with carrier, and removing the template agent. It features that the diameter and ration of big pores (5-2000 nm) can be controlled.

Description

technical field [0001] The invention relates to a heavy oil hydrogenation catalyst in which macropore structure parameters can be independently adjusted and a preparation method thereof. The catalyst is suitable for the catalytic hydrogenation process of heavy oil. Background technique [0002] Making full use of heavy oil resources and making them lighter to the maximum is the goal pursued by the oil refining industry, and catalytic hydrogenation of heavy oil is one of the important means of lightening heavy oil. Today, with the rapid development of social economy, the contradiction between the high content of non-hydrocarbon impurities in heavy oil, insufficient hydrogen content and stricter emission standards for fuel oil combustion in environmental legislation has become increasingly prominent. Catalytic hydrogenation of heavy oil has become an important means of clean fuel production. appear important. In the research of catalytic hydrogenation technology, the mass tr...

Claims

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Application Information

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IPC IPC(8): B01J32/00B01J37/00C04B38/06
Inventor 董鹏陈胜利王大军
Owner CHINA UNIV OF PETROLEUM (BEIJING)
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