The invention discloses an enhanced
Raman scattering (SERS) sensor based on a Ti3C2Tx / (001) TiO2 / W18O49 composite heterostructure and application of the SERS sensor, and relates to the technical field of micro-plastics and nano-plastics, and the SERS sensor is prepared by the following steps: dissolving LiF in HCl, stirring, adding Ti3AlC2, carrying out water bath reaction, centrifuging, washing, collecting Ti3C2Tx MXene precipitate,
drying, dispersing in deionized water, adding NaBF4 and HCl, stirring, carrying out ultrasonic treatment, reacting, filtering, washing, and
drying to obtain the SERS sensor based on the Ti3C2Tx / (001) TiO2 / W18O49 composite heterostructure, thus obtaining the SERS sensor based on the Ti3C2Tx / (001) TiO2 / W18O49 composite heterostructure. And centrifugally washing and
drying to obtain the Ti3C2Tx / (001) TiO2
powder. And adding the obtained Ti3C2Tx / (001) TiO2
powder into isopropanol, adding WCl6, stirring, reacting in a reaction kettle, carrying out centrifugal washing, carrying out suction
filtration on the Ti3C2Tx / (001) TiO2 / W18O49 on a
cellulose filter membrane, drying, and manufacturing the three-dimensional SERS sensor by using a puncher. The
detection limit of the sensor on
polystyrene (PS) particles is 25 mu g / mL, strong
linear correlation (R2 = 0.98) is shown, and the sensor can be used for analyzing an MNPs mixture of three components of PS,
polyethylene (PE) and
polypropylene (PP) and quantitatively detecting PS
microplastics in rainwater, soil and industrial
wastewater.