Petroleum hydrocarbon cracking carbon nine cut fraction hydrogenation technology
A technology for cracking carbon and petroleum hydrocarbons, used in hydrotreating process, petroleum industry, processing of hydrocarbon oil, etc., can solve the problems of long process, high raw material colloid, high energy consumption, and achieve the goal of inhibiting the reaction of polymerization and coke formation, gas and gas. Reasonable liquid distribution and the effect of improving effective utilization
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Embodiment 1
[0024] The catalyst used was supported on Al 2 o 3 -SiO 2 Ni-based catalysts. Catalyst specific surface area 180m 2 / g, the pore volume is 0.5ml / g, and it is a bimodal pore catalyst.
[0025] The composition of cracked carbon nine: the content of methyl styrene, styrene and other alkenyl aromatics and indene is 36%, the content of dicyclopentadiene is 32%, the content of tea is 3%, and the content of monoolefins, alkanes and others is 29%. The density is 0.948g / ml, the distillation range is 118~228℃, and the colloid is 4000mg / 100ml.
[0026] The above-mentioned part of cracked carbon nine is treated by pressure thermal polymerization method, the thermal polymerization pressure is 0.5-1.6Mpa, the temperature is 120-260°C, and the time is 8-20h. Composition of the produced flash oil: the content of methyl styrene, styrene and other alkenyl aromatics and indene is 7.8%, the content of dicyclopentadiene is 6.5%, and the content of monoolefins, alkanes and others is 85.7%; the...
Embodiment 2
[0033] Catalyst, flash oil are the same as embodiment 1, and rectification carbon nine adopts the product of table 1 serial number 5 of embodiment 1. In the 20,000-ton / year cracking C9 hydrogenation industrial unit, an upflow bubbling bed reactor is used for hydrogenation, and the colloid after mixing the flash oil and the rectified C9 is controlled at -1 . The results are shown in Table 3 and Table 4.
[0034] Entrance
temperature
℃
Bed temperature distribution °C
Total pressure Mpa
A
B
C
D
47.2
143.8
139.4
119.9
48.9
3.5
47
139.6
132.8
112.5
48.6
3.5
47.5
139.8
133.3
116
48.8
3.5
46.6
138.2
131.4
116
47.6
3.4
44.8
136.3
129.1
113.7
45.9
3.4
46.8
140.7
132.3
114.2
47.6
3.6
46...
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