Process for the production of polyethylene terephthalate copolyester, copolyester obtained thereby and its use and catalyst useful in the process

A technology of polyethylene terephthalate copolyester and terephthalic acid, applied in the field of catalyst composition of the method, can solve problems such as delay and use

Inactive Publication Date: 2007-05-09
SAUDI BASIC IND CORP SA
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

Isophthalic acid (IPA) is used as a comonomer to make bottle-grade PET, where it d

Method used

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Embodiment

[0042] The following examples are only used to illustrate the present invention. Of course, they are in no way considered to limit the scope of the present invention. Many changes and modifications can be made to the present invention.

[0043] Using the PTA method, various PETs were prepared in a small-scale reactor. All results are summarized in Table 1-5. First, the results of the antimony catalyst (200 ppm of Sb) used for the homopolyester are shown (Table 1). Next, the effect of the zinc catalyst on the homopolyester was demonstrated (Table 1). After that, a PET copolyester containing IPA was tested using antimony and zinc alone as a catalyst (Table 2). We also examined the PET copolymers containing IPA prepared with zinc catalysts and color correction ingredients (Table 3). Table 4 shows the SSP characteristics of IPA co PET (PET copolyester containing IPA) prepared with zinc. Table 5 shows some other polymer properties of IPA coPET prepared with color corrector.

[0044] Al...

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Abstract

The present invention relates to a process for the production of polyethylene terephthalate copolyester from terephthalic acid, isophthalic acid and ethylene glycol, comprising the steps of: a) preparing a catalyst composition comprising a zinc compound being present such that the elemental zinc content is in a range of about 50 to about 500 ppm, preferably about 200 to about 500 ppm, most preferably about 180 to about 260 ppm, based on the copolyester, b) placing the catalyst composition, terephthalic acid, isophthalic acid and ethylene glycol in a vessel, and c) reacting the terephthalic acid, isophthalic acid and ethylene glycol in an esterification step and a polycondensation step to obtain polyethylene terephthalate copolyester; to the copolyester obtained thereby and its use, as well as to a catalyst composition suitable in the inventive process.

Description

Technical field [0001] The present invention relates to a method for preparing polyethylene terephthalate copolyester, the obtained copolyester and its use, and a catalyst composition suitable for the method. Background technique [0002] PET is prepared in two steps by one of two methods, the DMT and PTA methods (or transesterification and direct esterification methods, respectively). Applications of PET include fiber and filament, film and bottle grade chips. Modern factories use the PTA method and, in addition, directly form products (fibers and filaments, films) by extruding the melt obtained from the final polycondensation reactor. [0003] First, let's compare DMT and PTA methods. The main difference is the starting material. Earlier methods used dimethyl terephthalate (DMT) and ethylene glycol (EG) as starting materials. This is because terephthalic acid of sufficient purity cannot be obtained in the early years of polyester preparation. In the DMT method, in the first ste...

Claims

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Application Information

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IPC IPC(8): C08G63/83C08G63/183C08G63/80D01F6/84C08J5/18D01F6/62
CPCC08G63/80D01F6/84C08G63/183C08G63/83D01F6/62C08G63/78
Inventor Z·贝希尔J·西迪基V·桑帕斯K·阿勒-卢海丹
Owner SAUDI BASIC IND CORP SA
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