Batch composition for producing low air bubble content, high permeability glass

A technology of glass batch material and air bubble content, applied in the field of glass batch material composition, can solve the problems of arsenic hazard, difficult management, arsenic environmental pollution, etc., and achieve the effect of reducing glass bubbles

Active Publication Date: 2007-05-16
江苏华东耀皮玻璃有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
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AI Technical Summary

Problems solved by technology

[0004] In the past, in order to reduce the air bubbles in the glass, arsenic was introduced into the glass batch as a clarifying agent, but arsenic will partially volatilize at high temperature and cause environmental pollution, and as a highly toxic substance, arsenic is difficult to manage. Therefore, with the continuous improvement of people's environmental requirements, more and more countries have begun to realize the harm of arsenic in glass. Developed countries such as Europe and Japan have strictly prohibited the use of arsenic in glass.

Method used

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Embodiment Construction

[0021] Antimony is a multivalent element with three valence states of +3, +4 and +5. It can be combined with oxygen at different temperatures to form antimony trioxide, antimony tetroxide or antimony pentoxide. When the temperature exceeds 380 degrees, antimony pentoxide will decompose into antimony trioxide and oxygen, and when the temperature is lower than 380 degrees, antimony trioxide will combine with oxygen to form antimony pentoxide, namely , antimony trioxide begins to boil at 1425 degrees and a large amount of volatilization occurs.

[0022] According to different glass production processes, different types of antimonates can be used. For example, in ultra-white glass (iron content less than 300ppm), since the melting temperature is not too high, and the glass is difficult to clarify, you can use a slightly higher decomposition temperature. Antimonate, such as sodium pyroantimonate or sodium metaantimonate, etc. The decomposition temperature of sodium pyroantimonate...

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Abstract

The invention discloses a fitting material composition to manufacture low-foam content and high transmission rate glass, which consists of necessary antimonite and selectable sulfate, wherein the antimonite can be antimony oxide, sodium antimonite or sodium pyroantimoniate; the sulfate is sodium sulfate, calcium sulfate and potassium sulfate. The weight percentage of antimonite corresponding to Sb2O3 is not less than 0.05% and weight percentage of sulfate corresponding to SO3 is not over 0.8%. The invention is fit for non-floating manufacturing pattern of glass.

Description

technical field [0001] The invention relates to a glass batch material composition, and the glass melted by using the composition has lower air bubble content and higher light transmittance. Background technique [0002] With the development of photovoltaic technology, it is necessary to use glass with high light transmittance and low bubble content as a protective panel. An important means to effectively increase the light transmittance of the glass is to reduce the iron content in the glass, and the reduction of the iron content will make the glass difficult to clarify. One of the important factors in glass quality is the bubbles contained in glass. Glass is melted at high temperature by mixing silica sand, soda ash, limestone and other raw materials together. The glass melted at high temperature is a kind of high viscosity liquid. Contains a large number of bubbles. When no clarifier is used, the content of carbon dioxide and nitrogen in the bubbles is the most, and they...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C03C3/087
CPCC03C3/087
Inventor 徐国平李志进杨卫民张贻安陈宏李亮佐杨奕张宝光薛忠社郜俊影
Owner 江苏华东耀皮玻璃有限公司
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