Developing roller and imaging apparatus comprising the same
A developing roller and surface coating technology, which is applied in the field of developing rollers and imaging devices, can solve problems such as increased compression set, large compression set, and toner melting, achieving low compression set, stable and excellent images, The effect of excellent resistance to toner melting
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preparation example Construction
[0073] (Preparation of roll body)
[0074] A urethane prepolymer having acetylene black dispersed therein was prepared as a component by mixing 100 parts by mass of a urethane prepolymer synthesized from toluene diisocyanate (TDI) and polyether polyol with 2 parts by mass of acetylene black Point A. On the other hand, 30 parts by mass of polyether polyol and 0.1 part by mass of sodium perchlorate (NaClO 4 ) was mixed while heating at 70°C, and it was further mixed with 4.5 parts by mass of polyether-modified silicone oil (foam stabilizer) and 0.2 parts by mass of dibutyltin dilaurate (catalyst) to form a mixture as component B. Subsequently, Component A and Component B were foamed by a mechanical foaming method and poured into a cylindrical mold in which a core was placed, followed by RIM molding to produce a roller comprising an elastic layer made of polyurethane foam body.
Embodiment 1
[0076] By adding 100 parts by mass of caprolactone-modified polyol (PCL205, produced by Daicel Chemical Industries, Ltd., molecular weight: 500), 35 parts by mass of carbon black and 50 parts by mass of cyanurate-modified HDI (Coronate HX, Produced by Nippon Polyurethane Industry Co., Ltd.) was dispersed in 300 parts by mass of methyl ethyl ketone (MEK) to prepare a coating composition for surface coating. The coating composition thus obtained was coated on the periphery of a roller body having an elastic layer made of polyurethane foam to form a surface coating, whereby a developing roller was produced. Then, the developing roller thus obtained was evaluated for roller resistance, 10-point average roughness (Rz), Asker C hardness and toner charging performance by known methods. In addition, the image forming performance was evaluated by assembling the developing roller in a laser printer to perform printing. The developing roller was also assembled in the ink cartridge and k...
Embodiment 2
[0078] By adding 100 parts by mass of caprolactone-modified polyol (PCL210N, produced by Daicel Chemical Industries, Ltd., molecular weight: 1000), 35 parts by mass of carbon black, and 50 parts by mass of cyanurate-modified HDI (Coronate HX, Produced by Nippon Polyurethane Industry Co., Ltd.) was dispersed in 300 parts by mass of MEK to prepare a coating composition for surface coating. A developing roller was prepared by using the coating composition thus obtained instead of the coating composition prepared in Example 1, and then evaluated. The results are shown in Table 1.
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