Abrasion resistant dental composition product and process

Abstract

Dental composition, product and process using a silicon containing abrasion resistant material. The dental products formed are abrasion resistant and self-lubricating across their entire cross sections. Dental compositions useful for forming dental products in accordance with the invention preferably includes an ethylenically unsaturated silane. The composition is formed into a dental prosthesis, such as an artificial tooth, inlay, onlay, facing, crown or bridge.

Description

[0001] This is a continuation-in-part of U.S. patent application Ser. No. 08 / 011,038 filed Jan. 29, 1993 which is incorporated herein by reference in its entirety, and which is a continuation-in-part of U.S. patent application Ser. No. 07 / 979,093 filed Nov. 19, 1992 which is incorporated herein by reference in its entirety, and a continuation-in-part of U.S. patent application Ser. No. 07 / 729,018, filed Jul. 12, 1991 which is incorporated herein by reference in its entirety.[0002] The invention relates to self-lubricating abrasion resistant compositions useful for a wide range of applications. Particular utility is found in the dental and medical arts where such compositions are suitable for the formation and construction of dental prosthesis such as artificial teeth, inlays, onlays, and facings, crowns and bridges and artificial bone parts and medical prosthetic body parts, such as knee joints and / or other bone engaged surfaces and the like where abrasion resistance, polishability ...

AI Technical Summary

Benefits of technology

[0050] It is an object of the invention to provide compositions which are useful in the construction of artificial teeth and other dental appliances, which compositions lead to products having superior physical and aesthetic characteristics.

[0056] The dental compositions of the invention are molded and polymerized to form dental prosthesis having reduced abrasive wear. While not wishing to be held to any theory describing the mechanism operative by which additions of self-lubricating monomer improves abrasion resistance, it is believed that silicon containing polymer or copolymers form domains upon polymerization and molding. It is hypothesized that as the dental composition is worn away new domains of the self-lubricating polymer or copolymer are exposed which smear over the surface of the molded article to occlude voids and provide a modified surface with lower friction and consequent improved abrasive wear resistance. Self-lubricating domains are small with particle sizes less than 3 .mu.m, preferably less than 1 .mu.m, may be sub-microscopic in dimension and are bonded to the matrix material. The dental products formed show improved abrasion resistance across their entire cross sections, that is, whether or not they are cut or sectioned. In a preferred embodiment material preferably is formed into a dental prosthesis, artificial tooth, inlay, onlay, facing, crown or bridge.

Problems solved by technology

In addition, the high cost of most noble metals from which many such appliances are commonly made leads to a cost consideration whenever their use is contemplated.

Ceramic materials, another common alternative, are often difficult to form into acceptable shapes, and may tend to be abrasive resulting in excessive wear upon contacting hard tissue, enamel and dentin.

Such materials are also difficult to polish satisfactorily.

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