Process for producing molten iron

a technology of molten iron and process, which is applied in the field of producing molten iron, can solve the problems of many problems to be solved, and achieve the effects of improving the metallization ratio of solids, and smooth melting operation

Inactive Publication Date: 2006-02-02
KOBE STEEL LTD
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AI Technical Summary

Benefits of technology

[0007] In practicing the above method, it is preferable to further comprise: feeding a powdery carbonaceous material onto the hearth of the moving-hearth reducing furnace as a hearth material; and then feeding the raw material mixture containing a carbonaceous reducing agent, an iron oxide-containing material and a CaO-containing material onto the hearth material. At the time, it is preferable to make an amount of the carbonaceous material fed as the hearth material, 30 kg or more per ton of the molten iron obtained in the melting furnace, for effectively increasing the metallization ratio of the solid reduced iron obtained in the reducing furnace.
[0008] It is also preferable to blend the CaO-containing material, whose entire amount is sufficient for making the basicity of the slag generated in the melting furnace 1.1 or more, with the raw material mixture and thus eliminate an amount of the CaO-containing material separately added into the melting furnace in result, for a smoother melting operation in the melting furnace; and it is further preferable to adjust the feeding amount of the carbonaceous material for hearth material in such a manner that an amount of the carbonaceous material of a non-combustion state fed into the melting furnace together with the solid reduced iron discharged from the reducing furnace becomes not less than an amount of the carbon aqueous material to be consumed in the melting furnace, for further reliable improvement in the metallization ratio of the solid reduced iron obtained in the reducing furnace, and for a more efficient and faster melting operation in the melting furnace.
[0009] It is also preferable to adjust a MgO content in the raw material mixture or to add MgO additionally into the melting furnace in such a manner that the slag generated in the melting furnace has a MgO content of 6 mass % or more, preferably 8 to 13 mass %, for effective suppression of refractory wear in using magnesia bricks as an inner lining refractory for the melting furnace. In this case, it is preferable to adjust a blending amount of CaO— and MgO-containing materials in the raw material mixture in such a manner that an amount of the slag-conditioning agents including CaO and MgO fed additionally into the melting furnace becomes 40 kg or less per ton of the molten iron obtained in the melting furnace.

Problems solved by technology

The direct iron making method using a moving-hearth reducing furnace connected to a melting furnace as described above has been studied for a fairly long period, but there are still many problems to be solved for operation in the industrial scale, for example, in operational stability, safety, cost, product quality (purity of molten iron), etc.

Method used

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  • Process for producing molten iron
  • Process for producing molten iron
  • Process for producing molten iron

Examples

Experimental program
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Effect test

example 1

[0063] In this experiment, as shown in the following Tables 1 and 2, two kinds of iron ores as iron oxide sources and one kind of coal as a carbonaceous reducing agent were used, and operational conditions were compared between when burnt line (CaO) was added previously to the raw material mixture (here, that is a compact in a pellet shape) to be fed into a rotary-hearth reducing furnace so that the slag formed in a melting furnace had a basicity of 1.6 respectively and when burnt lime was not added.

TABLE 1Major compositions and contents of iron ore (mass %)Iron oreTotal FeSiO2Al2O3CaOMgOSPOre (A)68.011.080.470.030.060.0020.041Ore (B)68.673.830.190.380.400.0020.024

[0064]

TABLE 2Composition of reducing agent (mass %)Reducing agentFCVMTATotalCoal71.519.98.6100

(Notes)

FC: Fixed Carbon, VM: Volatile Matter, TA: Total Ash

[0065] Raw material compacts (pellets) having the composition shown in Table 3 were formed by using the two kinds of iron ores and one kind of carbonaceous material sh...

example 2

[0079] In this example, used was an iron-bath melting furnace that uses the combustion heat of carbonaceous material as a heat source for melting a solid reduced iron. A furnace similar to oxygen top-blowing converter was used as the melting furnace, and oxygen for combustion of the carbonaceous material in the melting furnace was blown onto the molten iron from above by using a top-blowing lance. Specifically, conducted were two experiments: by a conventional method of adding into the melting furnace a CaO-containing material needed for controlling the slag basicity not being blended with a raw material compact; and by the present inventive method of blending all of the CaO-containing material with the raw material compact, where each method uses the same ore (A) as that used in Example 1 as an iron oxide source. Results are summarized in Table 5.

[0080] In the conventional method (1), the amount of CaO needed for adjusting the basicity of the slag generated in the melting furnace ...

example 3

[0084] In this example, shown is a typical method of,producing a solid reduced iron smaller in fluctuation and higher in metallization ratio by using a rotary-hearth reducing furnace. Namely, one case that the heat-reduction carried out by feeding 30 kg or more of a powdery carbonaceous material (per ton of molten iron obtained in the next melting furnace) onto the rotary hearth of a rotary-hearth reducing furnace as a hearth material and then by feeding the raw material pellet over the carbonaceous hearth material layer; and another case that the heat-reduction carried out by feeding only the raw material pellet directly onto the hearth without laying the powdery carbonaceous material onto the rotary-hearth; were compared. In either case, the residual carbon amount of the pellet and the metallization ratio were determined by collecting the raw material pellet under reduction from the sampling holes placed at different sites of the furnace, while maintaining the atmospheric temperat...

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Abstract

A high purity of molten iron is produced efficiently at a higher productivity, by feeding a raw material mixture containing a carbonaceous reducing agent, an iron oxide-containing material and a CaO-containing material onto a hearth of a moving-hearth reducing furnace, heat-reducing the raw material mixture in the reducing furnace, and melting it in a melting furnace melting, wherein a blending amount of the CaO-containing material in the raw material mixture is adjusted in such a manner that another feeding of the CaO-containing material into the melting furnace makes a basicity of a slag generated in the melting furnace 1.1 or more an feeding amount of the CaO-containing material becomes 40 kg or less per ton of the molten iron obtained in the melting furnace.

Description

FIELD OF THE INVENTION [0001] The present invention relates to a method of producing a molten iron, more specifically, a method of producing a molten iron by heat-reducing an iron oxide-containing material such as iron ore together with a carbonaceous reducing agent such as carbonaceous material in a moving-hearth reducing furnace and then melting a reduced iron obtained in a melting furnace in particular, which is improved to produce a high purity of molten iron efficiently at a higher productivity. DESCRIPTION OF THE RELATED ART [0002] As one of the recently developed direct iron making methods, known is a method of producing a molten iron by beat-reducing in a rotary type moving-hearth reducing furnace a mixture containing an iron oxide-containing material (iron source) such as iron ore and a carbonaceous reducing agent such as carbonaceous material, or a compact of the mixture containing carbonaceous material in a shape of pellet, briquette or the like, and then finally reducing...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C21B13/00C21B11/08C21B11/10C21B13/10
CPCC21B13/105C21B13/008Y02P10/134
Inventor ITO, SHUZOMIYAHARA, ITSUOTOKUDA, KOJI
Owner KOBE STEEL LTD
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