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Enhanced oil delivery from structured surfactant formulations

a technology of structured surfactant and enhanced oil, which is applied in the direction of detergent compounding agent, ampholytes/electroloneutral surface active compounds, hair cosmetics, etc., can solve the problems of unstable products containing high oil concentrations, and phase separation with tim

Inactive Publication Date: 2006-02-23
COLGATE PALMOLIVE CO
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention is about making new compositions that contain spherulites. These compositions have a surfactant component, salt, oil phase, and water. The surfactant component includes sodium trideceth sulfate, a structuring agent, a foam booster, and cationic guar gum. The technical effect of this invention is to provide new methods for making compositions that have spherulites, which can be useful in various applications such as industrial cleaning and personal care products.

Problems solved by technology

Body wash products can be very inefficient delivery vehicles for depositing hydrophobic actives and moisturizers on the skin's surface, since most of the hydrophobic actives are rinsed away during the washing process.
Current oil-in-water body wash formulas do not form stable products at high oil concentrations, since the oils and product aqueous base have significantly different densities.
Since micellar based body washes can have high viscosities, but not long range structure (substantially larger than the dimensions of the surfactant micelles themselves), products containing high concentrations of oil will be unstable and phase separate with time.
However, these systems can require heat to make, may be unstable at higher oil concentrations, and may result in a significant impairment of cleansing properties at low surfactant concentrations.
Addition of salts increases the size of the rod micelles thereof increasing zero shear viscosity (i.e., viscosity when sitting in bottle) which helps suspend particles but also increases critical shear rate (point at which product becomes shear thinning; higher critical shear rates means product is more difficult to pour).
To form such lamellar compositions, however, some compromises have to be made.
First, generally higher amounts of surfactant are required to form the lamellar phase.
Second, only certain surfactants will form this phase and, therefore, the choice of surfactants is restricted.
In short, lamellar compositions are generally more desirable (especially for suspending emollient and for providing consumer aesthetics), but more expensive in that they generally require more surfactant and are more restricted in the range of surfactants that can be used.
Again, however, they are generally more expensive to make (e.g., they are restricted as to which surfactants can be used and often require greater concentration of surfactants).

Method used

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  • Enhanced oil delivery from structured surfactant formulations
  • Enhanced oil delivery from structured surfactant formulations

Examples

Experimental program
Comparison scheme
Effect test

example 1a and 1b

[0046] Preliminary experiments using a standard wool binding assay were performed to determine whether changing surfactant phase structure from an oil in water emulsion to a spherulitic phase structure improved the delivery of oil to the skin's surface during washing FIG. 1 and Table 1). Initial experiments showed that at the same oil concentration of 10% and total surfactant concentration of 10.8%, a spherulitic surfactant system delivered approximately 4.5 times more oil the wool substrate compared to an oil in water emulsion formula (p≦0.05, FIG. 1).

example 1a

[0047] One particular method for making the invention is as follows. Note that the guar hydroxypropyl trimonium chloride (“HPTC”) (for example, as sold under the name Jaguar C-17 from Rhodia (Cranberry, N.J.)) is formed as a premix with water and mixed until fully hydrated and dispersed. The additional water in the formulation represents, 62.7 weight % of the final formula. The surfactant pre-mix which contains less than or equal to about 36 weight % sodium trideceth sulfate, less than or equal to about 10 weight % lauroamphoacetate, and less than or equal to about 6 to 11 weight % cocomonoethanolamide in water is selected. This surfactant premix can be obtained from Rhodia, and is similar to a commercial material MIRACARE SLB-365. The exact concentrations of the individual surfactant components can be modified to alter the surfactant concentrations in the final product. The surfactant premix is mixed with the Jaguar C-17 solution to yield a final concentration of the surfactant com...

example 1b

[0050] One particular method for making an oil in water emulsion is as follows. A primary phase of water is heated to 80 degrees C., and the hydroxypropylmethyl cellulose (available from Dow Chemical as METHOCEL® E4Ma) is added and mixed until fully dispersed. The decyl glucoside is then add and mixed completely. A second phase is formed by heating the sunflower oil to between 60 and 65 C, to which the acrylate crosspolymer (available as PEMULEN® TR1 from Noveon) is added, followed by dispersal with vigorous mixing. The second phase is then cooled to 60 degrees C., and the lauric acid is added. The second phase is then stirred for 30 minutes. The SLES is then added to the second phase with mixing, then all the additional ingredients for the oil in water emulsion listed in Table 1 are added in the order presented in Table 1. Each ingredient is completely mixed into the formula before the next ingredient is added. The sample is then cooled to below 40 C, and the preservative DMDMH is ...

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Abstract

Novel spherulite-containing compositions are described. Methods for making spherulite-containing compositions are also described. Preferred embodiments include compositions comprising a surfactant component, a salt, and an oil phase, wherein the surfactant component comprises (a) about 6 to about 10 weight % sodium trideceth sulfate; (b) about 1.8 to about 3.0 weight % of a structuring agent; (c) about 1.1 to about 3.0 weight % of a foam booster; (d) water; and (e) about 0.2 to about 0.8 weight % of a cationic guar gum.

Description

CROSS-REFERENCE TO RELATED APPLICATIONS [0001] This application claims benefit of U.S. Provisional Application No. 60 / 603,125, filed Aug. 19, 2004, the disclosure of which is hereby incorporated by reference herein in its entirety.FIELD OF THE INVENTION [0002] In certain aspects, the invention is directed to a novel approach to enhance the delivery of an oil phase to a substrate such as hair, skin or wool. Aspects of the invention use spherulite technology with selective incorporation of the oil phase after the spherulites are formed. BACKGROUND OF THE INVENTION [0003] Body wash products can be very inefficient delivery vehicles for depositing hydrophobic actives and moisturizers on the skin's surface, since most of the hydrophobic actives are rinsed away during the washing process. The majority of body wash products consist of entangled rod-like micelle formulas. Current oil-in-water body wash formulas do not form stable products at high oil concentrations, since the oils and produ...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): C11D17/00
CPCA61K8/0291A61Q5/02A61Q19/10C11D1/29C11D1/523C11D1/88C11D3/382C11D1/94C11D3/18C11D3/2079C11D3/2093C11D3/227C11D3/373C11D1/90A61K9/107
Inventor HILLIARD, PETER R. JR.SOLIMAN, NADIAHAUGK, PETER
Owner COLGATE PALMOLIVE CO
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