The invention provides a
lithium ion battery
anode material adopting an in-situ developed heterogeneous core-shell structure and a preparation method of the material. The
lithium ion battery
anode material is a composite with a
lithium-rich
lamellar phase material as a core layer and a heterogeneous
spinel phase generated on the surface of the core layer in an in-situ manner. The
lithium ion battery anode material is prepared in the steps as follows the lithium-rich
lamellar phase material containing Ni, Mn and M is prepared from
carbonate or hydroxides with a
coprecipitation method and then dispersed in a mixed
salt solution of Ni, Mn and M, the amount-of-substance ratio of Ni to Mn to M in the solution is the same with that in the lithium-rich
lamellar phase material, the
coprecipitation reaction is performed again, and the
mixed metal carbonate (or
metal hydroxide) coated lithium-rich lamellar phase material is obtained, the lithium-rich lamellar phase material is sintered at the high temperature in the absence of a Li source, and the
lithium ion battery anode material adopting the in-situ developed heterogeneous core-shell structure can be obtained. The
lithium ion battery anode material adopting the in-situ developed heterogeneous core-shell structure has the advantages as follows the shell layer coats the core layer in a uniform, complete and thickness-controllable manner, no obvious phase boundaries exist between the core layer and the shell layer, and the electrochemical performance of the material is improved.