The invention provides a
thermoplastic polyvinyl alcohol-based semi-interpenetrating network
composite material as well as a preparation method and application thereof, and belongs to the field of
high polymer material
processing. According to the method, a semi-interpenetrating
system is constructed through an amphiphilic
monomer dodecyl
methacrylamide acid self-assembled layered phase and a PVA /
polyacrylic acid linear hydrophilic network, PDIA hydrophobic
alkyl chains are subjected to cohesion to form a nanometer layered core, and carboxyl topology of the nanometer layered core is anchored to a PVA hydroxyl network;
acrylic acid is used as a non-amphiphilic component to provide a
hydrogen bond cross-linked skeleton and maintain the
dispersion stability of PDIA, and cooperates with a PDIA hydrophobic
chain segment to induce intercalation stripping of a
nanosheet layer. The structure triggers a dynamic sliding effect at the temperature of more than or equal to 100 DEG C, so that an
alkyl chain is recombined to reduce the
melt viscosity, a hot-pressing applicable
viscosity window of 104-105 Pa.s is maintained at the temperature of 100-130 DEG C, the inherent
processing window limitation and phase separation inhibition of PVA are synchronously broken through, and an industrial feasible scheme is provided for PVA hot-pressing molding.