Method to produce nanocrystalline powders of oxide-based phosphors for lighting applications

Abstract

Some embodiments of the present invention are directed toward nanocrystalline oxide-based phosphor materials, and methods for making same. Typically, such methods comprise a steric entrapment route for converting precursors into such phosphor material. In some embodiments, the nanocrystalline oxide-based phosphor materials are quantum splitting phosphors. In some or other embodiments, such nanocrystalline oxide based phosphor materials provide reduced scattering, leading to greater efficiency, when used in lighting applications.

Description

FEDERALLY SPONSORED RESEARCH [0001] The present invention was made with support from the Department of Energy, Contract Number DE-FC26.03NT41945.TECHNICAL FIELD [0002] The present invention relates generally to methods for preparing oxide-based phosphor materials, and more specifically to templated synthesis methods for preparing nanometer-scale oxide-based phosphor materials. BACKGROUND INFORMATION [0003] A luminescent material absorbs radiation from one region of the electromagnetic (EM) spectrum and emits radiation in another region of the electromagnetic spectrum, the emission generally being lower in energy than the absorption (i.e., Stokes shifted). A luminescent material in powder form is commonly called a phosphor, while a luminescent material in the form of a transparent solid body is commonly called a scintillator. [0004] Two broad classes of luminescent materials are generally recognized. These are self-activated luminescent materials and impurity-activated luminescent ma...

AI Technical Summary

Benefits of technology

[0017] In some or other embodiments, such nanocrystalline oxide based phosphor materials, by virtue of their nanocrystallinity, provide reduced scattering—leading to greater efficiency when used in fluorescent or other lighting applications. Other applications for such phosphor materials of the present invention, include, but are not limited to, their combination with light-emitting diode (LED) devices, where the phosphors serve to tune the emission of the LED.

Problems solved by technology

However, fluoride-based compounds do not have sufficient stability to permit their use as phosphors in fluorescent lamps because they are known to react with mercury vapor that is used in such lamps to provide the UV radiation.

In addition, producing fluoride-based materials presents a great practical challenge because it involves the use of large quantities of highly reactive and toxic fluorine-based materials.

However, the high toxicity associated with Cd-containing materials has led to legislation precluding the use of such phosphors.

While the above-mentioned oxide-based quantum-splitting phosphors overcome many of the limitations of halide-based quantum splitting phosphors, they generally have particle sizes large enough to scatter 254 nanometer (nm) radiation and would thereby decrease the efficiency of fluorescent lamps in which they are used.

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