Scr catalyst for removal of nitrogen oxides

Inactive Publication Date: 2009-06-04
KOREA INST OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0020]According to the present invention, antimony is added to promote the reactivity at low temperatures and the sulfur poisoning resistance. Preferably, 0.5-6 wt. % of antimony is added. B

Problems solved by technology

The produced ammonium bisulfate salts are imbedded into the surfaces of the catalysts, thereby interfering with the reduction reaction.
As a result, as the amount of unreacted ammonia increases, formation of sulfur trioxides (SO3) is promoted, thereby accelerating the sulfur poisoning, which eventually shorten the life of the catalysts.
%, the increase in the price of catalysts is unavoidable.
A conventional art uses a TiO2 supporter impregnat

Method used

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  • Scr catalyst for removal of nitrogen oxides
  • Scr catalyst for removal of nitrogen oxides
  • Scr catalyst for removal of nitrogen oxides

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Embodiment Construction

[0026]The present invention will be further illustrated by the following examples in order to provide a better understanding of the invention. However, the present invention is not limited to the examples, and particularly, the substances that compose each layer can be other substances that are within the technical effect of the present invention.

[0027]FIG. 1 shows NO conversion without the presence of antimony according to Reference 1 (standard 1) and one with antimony at different temperatures according to Example 1 (type 1) of the present invention.

[0028]Reference 1 uses titanium oxide (TiO2) carrier, without antimony added and impregnated with 2 wt. % of vanadium as an active material. Example 1 uses titanium oxide (TiO2) carrier which is impregnated with 2 wt. % of vanadium as an active material and 2 wt. % of antimony oxide as a minor catalyst. The amounts of nitrogen oxides and ammonia used are each 800 ppm, the amount of water is 6%, and the amount of oxygen is 3%.

[0029]FIG....

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Abstract

The present invention provides for catalysts for selective catalytic reduction of nitrogen oxides. The catalysts comprise metal oxide supporters, vanadium, an active material, and antimony, a promoter that acts as a catalyst for reduction of nitrogen oxides, and at the same time, can promote higher sulfur poisoning resistance and low temperature catalytic activity. The amount of antimony of the catalysts is preferably 0.5-7 wt %.

Description

TECHNICAL FIELD[0001]The present invention relates to catalysts for selective reduction of nitrogen oxides, and more particularly to catalysts for removal of nitrogen oxides that have enhancing effects on the reduction activity of nitrogen oxides at low temperatures and on the sulfur poisoning resistance.BACKGROUND ART[0002]Nitrogen oxides (NOx) are usually produced when fuels are combusted, and are exhausted from moving sources such as a motor vehicle and fixed sources such as a power plant or an incinerator. These nitrogen compounds are identified as the major causes of acid rain and smog formation. Since environmental protection regulations have become stricter recently, more studies are being carried out, in response, in order to reduce nitrogen compounds through catalysts.[0003]As a method of removing nitrogen compounds that were emitted from fixed sources, selective catalytic reduction (SCR) device that uses vanadium oxides (V2O5) as active materials impregnated on a titanium ...

Claims

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Application Information

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IPC IPC(8): B01J21/06B01J23/22B01J21/04B01J23/16
CPCB01D53/8628B01D53/9418B01D2251/2062B01D2255/2098B01J23/22B01D2255/20707B01D2255/20723B01J23/18B01J23/20B01J23/644
Inventor HA, HEON-PHILCHUNG, SOON-HYOOH, YOUNG-JOO
Owner KOREA INST OF SCI & TECH
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