The invention relates to the technical field of denitration catalytic materials, and discloses a preparation method of a denitration catalytic material special for emission of a
methanol internal combustion engine, and the preparation method comprises the following steps: S1, preparing a multi-element synergistic precursor
mixed solution: sequentially mixing a carrier precursor, an active
metal salt, a main ligand, a double-dynamic auxiliary ligand and a coordination
regulator to obtain the multi-element synergistic precursor
mixed solution; adjusting the pH value, and stirring to obtain a transparent and uniform multi-element synergistic precursor
mixed solution; s2, gradient
coordination polymerization reaction: putting the multi-element synergistic precursor mixed solution into a closed high-pressure reaction kettle, and reacting by adopting a stepped heating
polymerization process to obtain an integrated gel product; s3,
doping gas assisted low-temperature
plasma activation; and S4, surface acid-base modification post-treatment. Through the synergistic effect of the double-dynamic auxiliary ligand and the coordination
regulator, the gradient
coordination polymerization process is matched to regulate and control the precursor structure, the reaction
induction period is shortened, the
NO conversion rate in the low-temperature interval is increased, and the problem that the low-temperature exhaust denitration
reaction speed of the
methanol internal combustion engine is low is solved.