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Composition for Filtering and Removing Particles and/or Constituents from a Fluid

a technology of fluids and components, applied in the field of filtering and removing particles and/or constituents from fluids, can solve the problems of increasing the capacity of cake to entrap additional debris, increasing the capacity of cake to swell and thicken, and buoyant filtration media particles, etc., and achieve the effect of less susceptible to separation

Inactive Publication Date: 2009-10-22
WORLD MINERALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

[0021]In certain embodiments, an in-situ precipitation process may be used to create a filterable composite adsorbent having relatively small particle-sized adsorbent components, for example, less than 1 micrometer, on the surface of at least one filtration component. Consequently, the filter-aid materials comprising at least one filterable composite adsorbent disclosed herein may provide a greater adsorptive surface area than prior implementations, thereby enabling the filter-aid materials to adsorb a greater amount of particles and / or constituents from a fluid than was previously possible. The adsorptive effectiveness of the filter-aid materials comprising at least one filterable composite adsorbent disclosed herein may be evidenced by a lower level of turbidity in the filtered fluid than could previously be achieved.
[0027]The filter-aid materials comprising at least one filterable composite adsorbent disclosed herein also may exhibit various wet densities. For example, the filter-aid material comprising at least one filterable composite adsorbent may have a wet density ranging from about 10 to about 25 lb / ft3. As wet density reflects the void volume of the adsorbent component to entertain matter in the filtration process, a lower wet density may indicate that the adsorbent component has a high void volume and thus can adsorb more particles and / or constituents in the fluid.

Problems solved by technology

That additional layer of filter-aid material causes the filter cake to swell and thicken and increases the capacity of the cake to entrap additional debris.
Those intricate and porous structures create networks of void spaces that may result in buoyant filtration media particles that have apparent densities similar to those of the fluids in which they are suspended.
However, while well suited for the task of removing particulate matter by physical entrapment, those porous filtration components may not be as well suited for the task of removing particulate matter from a fluid by the process of adsorption and are thus often times used in combination with an adsorbent component.
Diatomite products have an inherently intricate and porous structure composed primarily of silica.
As the permeability of the filtration component decreases, the ability of the filter-aid material to remove small particles may increase, but often at the expense of a slower flow rate through the filter-aid material.
Conversely, as the filtration component permeability increases, the ability of the filter-aid material to filter particles may decrease and, consequently, the fluid flow through the filter-aid material increases.
The reacted proteins and / or polyphenols may then grow to large particles, which causes the beer to become turbid, a condition also known as “chill-haze.” Chill-haze may be undesirable to both consumers and brewers.
Filtration processes that implement both an adsorption step and a filtration step may be less efficient because of the difficulties of filtering the adsorbent components.
That occupancy may reduce the permeability of the filter-aid material, leading to an overall lower filtration flow rate.
Simple mixtures may be somewhat ineffective as the components may be subject to separation due to physical distress often experienced in packaging and shipping.
Although Palm discloses a filterable composite adsorbent, it does not disclose a filterable composite adsorbent where the adsorbent components have a smaller average particle size, such as 1 micron or smaller.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example 1

[0087]The following procedure was used to prepare several filterable composite adsorbents for evaluation. In each case, a sodium silicate solution with a SiO2:Na2O weight ratio of 3.2 to 1 was selected based on a combination of efficiency and price, but other ratios of SiO2:Na2O may also be used. The sodium silicate was added to reverse osmosis water with a concentration of about 2%. A quantity of sulfuric acid (H2SO4) was then added to the slurry to reduce the pH to about 5.5 to 9. A filtration component was then added to the solution. In this example, the filtration component was Harborlite® 200, an expanded milled perlite with a permeability of 0.29 Da and a wet density of about 14.0 lbs / ft3. The amount of filtration component added was based upon the desired amount of silica gel in the end chill-proofing filter-aid product. The slurry was stirred until gelling occurred (about 25-60 minutes depending upon the pH level). Next, water was added to disperse the gelled slurry. The slu...

example 2

[0089]The procedure of Example 1 was repeated, except that Celite Standard Super-Cel® and Celite Hyflo Super-Cel® were used as filtration components in the place of the Harborlite® 200. Celite Standard Super-Cel® filtration component is a diatomite-based filtration component with a permeability of 0.25 Da and a wet density of about 9 lbs / ft3. Celite Hyflo Super-Cel® filtration component is also diatomite based, but has a permeability of 1.10 Da and a wet density of 10 lbs / ft3.

[0090]Table 2 shows the filtration properties of a diatomite-based chill-proofing filter-aid using different amounts of silica gel and at different pH levels. The base materials were Celite Hyflo Super-Cel® and Celite Standard Super-Cel® diatomite. It is shown that the relative amount of silica gel precipitated upon the filtration component had a direct relationship with the BET surface area of the adsorbent component.

[0091]Table 3 shows the performance of a diatomite based chill-proofing aid of Table 2. The fi...

example 3

[0093]The procedure of Example 2 was repeated with the exception of replacing the sodium silicate solution used in Example 2 with a commercial sodium silicate solution. Again, different filtration components were used in the process to create the filterable composite adsorbent (Celite Standard Super-Cel®, Celite Hyflo Super-Cel®, and Celite 512®).

[0094]Tables 5-8 show the performance of a commercial non-diatomite based sodium silicate. In Tables 5-7, the commercial sodium silicate solution used was PQ N-Clear®, manufactured by PQ Corporation of Valley Forge, Pa. PQ N-Clear® has a SiO2:Na2 ratio of 3.22:1 and a pH of 11.3. In Table 8, the commercial sodium silicate solution used was PQ N®, manufactured by PQ Corporation of Valley Forge, Pa. Table 5 reflects a chill-proofing filtration component formed by Celite Hyflo Super-Cel®. Table 6 reflects Celite Standard Super-Cel® as the filtration component. Table 7 reflects Celite 512® as the filtration component. Celite 512® has a permeabi...

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PUM

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Abstract

Filter-aid materials are disclosed herein, and processes, systems, and methods using such filter-aid materials for filtering and removing particles and / or constituents from a fluid, wherein the filter-aid material comprises at least one filterable composite adsorbent comprising at least one adsorbent component formed in-situ on at least one filtration component. Further disclosed herein are filter-aid materials and processes, systems, and methods using such filter-aid materials for filtering and removing particles and / or constituents from a fluid, wherein the filter-aid material comprises at least one filterable composite adsorbent comprising at least one adsorbent component formed in-situ on at least one filtration component, and wherein the filter-aid material further comprises an at least one additional filtration component mixed with the at least one filterable composite adsorbent.

Description

RELATED APPLICATIONS[0001]This application incorporates by reference in their entireties U.S. Provisional Application Nos. 60 / 830,781 filed Jul. 14, 2006, and 60 / 945,954 filed Jun. 25, 2007.FIELD OF THE INVENTION[0002]Disclosed herein are filter-aid materials and processes, systems, and methods using such filter-aid materials for filtering and removing particles and / or constituents from a fluid, wherein the filter-aid material comprises at least one filterable composite adsorbent comprising at least one adsorbent component formed in-situ on at least one filtration component. Also disclosed herein are filter-aid materials and processes, systems, and methods using such filter-aid materials for filtering and removing particles and / or constituents from a fluid, wherein the filter-aid material comprises at least one filterable composite adsorbent comprising at least one filtration component (such as a siliceous material) and at least one adsorbent component (such as a precipitated silica...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): B01D37/02
CPCC02F1/28C02F1/281C02F2303/20C02F1/288C02F2209/11C02F1/286C12H1/063B01D37/025B01D39/2068B01D2239/0478B01D2239/1291
Inventor HU, QINGCHUNNYAMEKYE, GEORGE A.REES, ROBERT H.MASTRUP, NIELS S.TIHOMIROV, LARISAPAVLAKOVICH, WALTER N.
Owner WORLD MINERALS
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