Non-ferrous metal cover gases

Abstract

Disclosed are cover gas compositions comprising fluoroolefins for impeding the oxidation of molten nonferrous metals and alloys, such as magnesium. The cover gas compositions can include at least one fluoroolefin and a carrier gas.

Description

RELATED APPLICATIONS[0001]This application is a continuation-in-part of U.S. application Ser. No. 11 / 691,276, filed on Mar. 26, 2007, currently pending, which claims the priority of U.S. Provisional Application No. 60 / 818,416, filed on Jul. 3, 2006. The contents of U.S. application Ser. No. 11 / 691,276 and U.S. Provisional Application No. 60 / 818,416 are incorporated herein by reference in their entirety.FIELD OF THE INVENTION[0002]The present technology relates to cover gas compositions for molten nonferrous metal, such as magnesium, and methods of using the same to prevent the oxidation when the metal is exposed to air.DESCRIPTION OF RELATED ART[0003]Certain non-ferrous metals, such as magnesium, aluminum, and lithium, are highly reactive and oxidatively unstable. For example, molten magnesium is readily and violently oxidized in ambient air or dry air, burning with a flame temperature of approximately 2820° C. Three approaches have been suggested to inhibit these severe oxidation p...

AI Technical Summary

Benefits of technology

[0023]In addition, this present technology relates to molten reactive metal having a protective film on its surface that is formed by a reaction between the metal and a composition containing an effective amount of fluoroolefin of the present technology, preferably said amount being effective under the intended circumstances to at least partially passivate the surface of the metal, thereby reducing the chemical reactivity of the metal, especially the metal's oxidative reactivity.

[0024]According to another aspect of the present technology, methods are provided for impeding the oxidation of a molten nonferrous metal exposed to and oxygen-containing gas, such as air, comprising: (a) providing molten nonferrous metal, such as magnesium, having a surface; (b) exposing said surface to a cover gas composition that includes at least one fluoroolefin of the present technology, preferably a gas containing one or more of trans-HFO-1234ze, cis-HFO-1225ye, HFCO-1233xf, cis-HFCO-1233zd, and trans-HFCO-1233zd; and optionally (c) forming a protective film on said surface, which can be an oxidized film. In certain preferred aspects of the method, the exposed surface of the molten reactive metal can be exposed to or contacted with the gaseous fluoroolefin composition. Without being bound by or to any particular theory of operation, it is believed that the fluoroolefin composition in preferred embodiments reacts with the metal to produce an oxidatively stable film on its surface. By forming this film, the oxygen in the air can be effectively separated from the surface of the molten reactive metal and thus prevent or at least substantially inhibit the oxidation of the metal by the oxygen.

Problems solved by technology

Certain non-ferrous metals, such as magnesium, aluminum, and lithium, are highly reactive and oxidatively unstable.

However, SF6 suffers from several disadvantages, including: its sulfur-based decomposition products at high temperature are very toxic; it is expensive and has limited sources of supply; and it is a known greenhouse gas having, at a time horizon of 100 years, a Global Warming Potential (GWP) of 23,900 relative to 1 for carbon dioxide.

It is also noted that once magnesium has ignited, the resulting fire cannot be extinguished even with high concentrations of SF6.

The potential byproduct SO, is even worse in this respect as it can accelerate a magnesium fire.

However, this material tends to be very expensive and is also very toxic.

For example, it has heretofore been believed that fluoroolefins are undesirable as cover gases due to environmental and / or toxicity concerns.

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