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Method for producing lubricating base oil with low cloud point and high viscosity index

a technology of lubricating base oil and low cloud point, which is applied in the direction of hydrocarbon oil treatment products, metal/metal-oxide/metal-hydroxide catalysts, physical/chemical process catalysts, etc., can solve the problems of increasing the pour point and cloud point drop, reducing yield and viscosity of the base oil product, etc., and achieving low pour point , low aromatic content, low cost

Inactive Publication Date: 2013-09-26
PETROCHINA CO LTD +1
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention provides a method for making a lubricating oil with low cloud point and high viscosity index. This is done by using a raw material of highly waxy heavy fraction oil with specific properties. The method involves a three-stage hydrogenation process, which includes hydrogenation pre-refining, isomerization, and supplementary refining. The resulting lubricating oil has the desired properties of low pour point and high viscosity index.

Problems solved by technology

The pour point of a light deasphalted hydrotreated oil can be lowered from 9° C. to −24° C., and the cloud point can be lowered from 12° C. to −16° C. The method has the following obvious disadvantage: the yield and the viscosity of the base oil product will be greatly decreased when the wax content in the feed stock is high, and the drops of the pour point and the cloud point need to be increased.

Method used

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  • Method for producing lubricating base oil with low cloud point and high viscosity index
  • Method for producing lubricating base oil with low cloud point and high viscosity index
  • Method for producing lubricating base oil with low cloud point and high viscosity index

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example 1

[0033]According to the process shown in FIG. 4, the experimental device and the feed stock were the same as those in Comparative Example 1. The other reaction conditions were the same as those in Comparative Example 1 except that the reaction temperature of isomerization / asymmetrical cracking was 351° C., and the space velocity was 0.75 h−1. The reaction conditions of Comparative Example 1 are shown in Table 3.

[0034]Product distribution comparison of Example 1 and Comparative Example 1 is shown in Table 4, and main product properties are shown in Table 5.

[0035]According to the process shown in FIG. 4, paraffin base 200SN lightly dewaxed oil was used as a feed stock in the experimental device of Comparative Example 1, and the physical and chemical properties of the feed stock are shown in Table 2. The reaction conditions are shown in Table 3.

TABLE 2Properties of feed stocks of ComparativeExample 1 and Example 1650SNAnalysisItemFurfural Refined OilMethod20° C. Density, g / cm30.8721GB / T...

example 2

[0038]The process, experimental device and feed stock were the same as those in Comparative Example 2. The other reaction conditions were the same as those in Comparative Example 2 except that the temperature of the isomerization / asymmetrical cracking reaction was 325° C., and the liquid hourly space velocity was 1.2 h−1.

[0039]The product distributions of the reactions of Example 2 and Comparative Example 2 are shown in Table 8, and main properties of the products are shown in Table 9.

[0040]It can be seen from Tables 6 to 9 and FIG. 2 that compared with Comparative Example 2, the method of Example 2 has significant features of a hydrorefining-isomerization / asymmetrical cracking-hydrofinishing, that is, the yield of a heavy base oil (5 cst base oil) is high, and the yields of small-molecule products (gas and naphtha) and big-molecule products (10 cst base oil) are both high, and are up to 19.96% and 73.3% respectively, the yields of diesel oil and a light base oil (2 cst base oil) ar...

example 3

[0041]According to the process shown in FIG. 4, the experimental device is the same as that in Comparative Example 1, and the feed stock is a 100N cerate obtained from crude oil by processes of reduced-pressure distillation, furfural refining and acetone-toluene dewaxing, of which the physical and chemical properties are shown in Table 10. Under the process conditions shown in Table 11, the resulting product distribution is shown in Table 12, and the main properties of the products are shown in Table 13.

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Abstract

The present invention relates to a method for producing lubricating base oil with a low cloud point and a high viscosity index. In the method, a lubricating base oil with a low pour point, a low cloud point and a high viscosity index is produced by a hydrorefining-isomerization / asymmetrical cracking-hydrofinishing in the presence of hydrogen, wherein a highly waxy heavy fraction oil having an initial boiling point of 300° C. to 460° C., a wax content of 5% or more, a pour point of −20° C. or more and a cloud point of −5° C. or more is used as a raw material, and naphtha and middle fraction oil being co-produced. The method is characterized mainly in the high yield of heavy base oil, a low pour point and cloud point, a high viscosity and viscosity index of the base oil.

Description

FIELD OF THE INVENTION[0001]The present invention relates to a method for producing a lubricating base oil with a low cloud point (<−5° C.) and a high viscosity index (>120).BACKGROUND OF THE INVENTION[0002]Patent CN101134910A discloses a method for lowering the pour point and the cloud point of a lubricating oil distillate. In the method, a catalytic dewaxing process is adopted, and the catalyst includes nickel metal as an active component, which is contained in a support of a ZSM-5 molecular sieve. The pour point of a light deasphalted hydrotreated oil can be lowered from 9° C. to −24° C., and the cloud point can be lowered from 12° C. to −16° C. The method has the following obvious disadvantage: the yield and the viscosity of the base oil product will be greatly decreased when the wax content in the feed stock is high, and the drops of the pour point and the cloud point need to be increased.[0003]Patent CN1524929 discloses a method for lowering the cloud point of a lubricat...

Claims

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Application Information

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IPC IPC(8): C10G69/02
CPCC10G67/02C10M177/00C10G2300/4018C10G2300/1022C10G2300/1074C10G69/02C10G2300/302C10G2300/304C10G2400/02C10G2400/10C10G2300/301C10G45/08C10G45/58C10G47/18C10G65/12B01J23/42B01J29/005B01J29/44B01J29/7484B01J29/7492B01J29/85B01J35/638B01J35/635B01J35/615C10M5/00C10G65/04
Inventor HU, SHENGTIAN, ZHIJIANYAN, LIJUNLI, WENLEXU, YUNPENGCHI, KEBINMENG, XIANGBINWANG, BINGCHUNTAN, MINGWEIWANG, LEILIU, YANFENGZHU, JINLINGGAO, SHANBIN
Owner PETROCHINA CO LTD