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Variable transmittance optical filter with substantially co-planar electrode system

a transmittance optical filter and substantially co-planar electrode technology, applied in the direction of static indicating devices, door/window protective devices, instruments, etc., can solve the problems of difficult manipulation for users, drawing blinds, and windows made using electrochromic technology can be quite expensiv

Inactive Publication Date: 2013-10-17
SWITCH MATERIALS
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The present invention relates to variable transmittance optical filters that can change from a first state to a second state by applying an electric voltage. The filters comprise a first layer with a co-planar electrode system made of transparent electrically conductive material, a second layer proximate to the first layer and comprising a transition material that can vary the degree of visible light transmittance, and an electrical connection system for electrically connecting the electrodes to a source of electric voltage. The filters can be used to control the amount of light transmitted through them. The invention also provides methods for preparing the filters and transitioning the transition material. The technical effects of the invention include the ability to create optical filters that can change from a dark state to a faded state with a simple reversal of the polarity of the voltage applied to the electrodes, and the use of finger-like structures on the electrodes to improve the transition between states.

Problems solved by technology

‘Panoramic’ sunroofs may be installed to provide visibility to occupants (e.g. for sightseeing—‘dome roofs’) and provide a feeling of ‘being outside’, a drawn blind does not accommodate this desire, and for a large roof or dome, may be difficult for a user to manipulate at will.
As such, windows made using electrochromic technology can be quite expensive.

Method used

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  • Variable transmittance optical filter with substantially co-planar electrode system
  • Variable transmittance optical filter with substantially co-planar electrode system
  • Variable transmittance optical filter with substantially co-planar electrode system

Examples

Experimental program
Comparison scheme
Effect test

example 1

Preparation of Selected Hybrid P / E Compounds

[0203]S001 and S002 were prepared as described in U.S. Pat. No. 7,777,055.

Synthesis of S042—

[0204]

Synthesis of 3-bromo-2,5-bis(4-(tert-butyl)phenyl)thiophene: (30)

[0205]Sodium carbonate monohydrate (58.0 g, 468 mmol) was dissolved in water (500 mL) and a solution of 4-(tert-butyl)-phenylboronic acid (40.0 g) and 2,3,5-tribromothiophene (30.0 g, 94 mmol) in THF (500 mL) was added, and deoxygenated by bubbling with argon. Pd(PPh3)4 (5.0 g, 4.30 mmol) was added and the mixture refluxed for 24 h. The mixture was cooled and the aqueous phase separated and extracted with EtOAc. Organic fractions were combined washed with water (500 mL) and dried over MgSO4. The solvent was evaporated and the crude product washed in MeOH, filtered and dried overnight to afford a light yellow, powdery solid (35.46 g, 89%).

Synthesis of S042

[0206](3,3′-(perfluorocyclopent-1-ene-1,2-diyl)bis(2,5-bis(4-(tert-butyl)phenyl)thiophene.): A solution of (30) in anhydrous TH...

example 2

Preparation and Testing of Variable Transmittance Optical Filters with an Interdigitated SC Electrode System Comprising Symmetric Electrode Widths

[0213]Six variable transmittance optical filters comprising different interdigitated SC electrode systems were prepared as follows. A test wafer was formed from a piece of ITO-coated glass purchased from Delta Technologies (Stillwater, Minn.). Areas with symmetric interdigitated electrodes were created in which both first and second electrodes and bus bars were of equal size, with spacing and electrode digit width as indicated in Table 1. A photoresist layout of the electrode patterns was created with CAD, a suitable photomask produced and the pattern wet-etched into the ITO coating using standard photolithographic techniques. Briefly, the substrate was cleaned with acetone and isopropyl alcohol, and AZ™ MIR™ 703 resist spincoated at 4000 rpm and baked at 90° C. for 60 seconds (following manufacturer's instructions). The electrode patterns...

example 3

Preparation and Testing of Variable Transmittance Optical Filters with an SC Electrode System Comprising Asymmetric Electrode Widths

[0216]This example describes the preparation and testing of variable transmittance optical filters in which the SC electrode system of the variable transmittance optical system is patterned asymmetrically. A first electrode comprises fingers that are wider than those of the second electrode, providing a greater square area for the first electrode relative to the second electrode. In devices comprising a hybrid P / E switching material where the larger electrode is the anode (positive potential) and the smaller electrode is the cathode (negative potential), all, or substantially all, of the area of the device can be electrofaded. This example demonstrates that an asymmetric interdigitated electrode pattern can provide better uniformity while electrofading the switching material, with a smaller electrode area, and in some applications, a reduced need for et...

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Abstract

A variable transmittance optical filter comprising: a first layer comprising a first substantially transparent substrate with a substantially co-planar (SC) electrode system disposed thereon, the SC electrode system made of transparent electrically conductive material and comprising at least one pair of electrically separate electrodes arranged in a substantially co-planar manner on the first substantially transparent substrate, each pair of electrically separate electrodes comprising a first electrode and a second electrode, a second layer proximate to the first layer and comprising a transition material that darkens in response to a non-electrical stimulus and lightens in response to application of an electric voltage; and an electrical connection system for electrically connecting the SC electrode system to a source of electric voltage.

Description

RELATED CASES[0001]This application claims the benefit of U.S. Provisional Application No. 61 / 423,536 filed Dec. 15, 2010, which is incorporated herein by reference in its entirety.FIELD OF THE INVENTION[0002]The present invention relates to the field of variable transmittance optical filters, in particular to those comprising an optical filter capable of transitioning from one state of visible light transmittance to another with application of an electric voltage to a substantially co-planar electrode system.BACKGROUND OF THE INVENTION[0003]Optical filters are widely used to control visible and solar energy. Most notably, optical filters have been used as glazings in window technology (e.g. windows of buildings, vehicles, aircraft, spacecraft, ships or the lie) to control the flow of light and heat into and out of the glazing, for glare reduction and energy load management. Improving the energy efficiency of buildings is a key aspect of reducing energy use and reducing CO2 emission...

Claims

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Application Information

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Patent Type & Authority Applications(United States)
IPC IPC(8): G02F1/155G02F1/1516
CPCG02F1/155E06B9/24E06B2009/2464G02C7/101G02C7/102G02F2001/1552G02F2001/1557G02F2201/124G02F1/0126G02F1/03C07D495/04G02F1/1516G02F1/163G09G3/38G02F1/153C08G2261/54G02F2001/15145G02B5/23E06B2009/2417E06B2009/247G02F1/1506
Inventor LAM, DUHANEBRANDA, NEIL ROBIN
Owner SWITCH MATERIALS