Curable resin film and first protective film forming sheet
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manufacturing example 1
[0590](Manufacturing of Pressure-Sensitive Adhesive Resin (I-2a))
[0591]A polymerization reaction was performed so as to obtain an acrylic polymer by using 2-ethylhexyl acrylate (hereinafter, abbreviated as “2EHA”) (80 parts by mass) and HEA (20 parts by mass) as raw materials of a copolymer.
[0592]2-methacryloyloxyethyl isocyanate (hereinafter, abbreviated as “MOI”) (22 parts by mass, approximately 80 mol % with respect to HEA) was added to the acrylic polymer, and an addition reaction was performed at 50° C. for 48 hours in an air stream so as to obtain a target pressure-sensitive adhesive resin (I-2a).
example 1
[0593]
[0594](Manufacturing of Thermosetting Resin Layer Forming Composition)
[0595]The polymer component (A)-1, the epoxy resin (B1)-1, the epoxy resin (B1)-2, the epoxy resin (B1)-3, the thermal curing agent (B2)-1, the curing accelerator (C)-1, and the filler (D)-1 were dissolved or dispersed in methyl ethyl ketone such that the ratios of these amounts are the values indicated in the following Table 1, and stirred at 23° C. so as to obtain a resin layer forming composition (III-1) having the solid content concentration of 55% by mass as a thermosetting resin layer forming composition.
[0596]Note that, the description “-” in the column of contained components in the following Table 1 means that the thermosetting resin layer forming composition does not contain that component.
[0597](Manufacturing of First Pressure-Sensitive Adhesive Composition)
[0598]As an isocyanate crosslinking agent, a tolylene diisocyanate trimer adduct of trimethylolpropane (“Coronate L” manufactured by Tosoh Cor...
example 2
[0630]A first protective film forming sheet was manufactured in the same method as that used in Example 1 except that the contained component and the amount of the thermosetting resin layer forming composition were set as indicated in Table 1, and a cured material of the thermosetting resin film was evaluated. The results are indicated in Table 1.
[0631]
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