Colored photosensitive resin composition and multilayer cured film prepared therefrom
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Preparation Example 1: Preparation of a First Copolymer (A1-1)
[0248]A 500-ml, round-bottomed flask equipped with a refluxing condenser and a stirrer was charged with 100 g of a monomer mixture composed of 23% by mole of methacrylic acid, 43% by mole of styrene, 9% by mole of glycidyl methacrylate, and 25% by mole of methyl methacrylate, along with 2 g of 2,2′-azobis(2,4-dimethylvaleronitrile) as a radical polymerization initiator, which mixture was dissolved in 300 g of propylene glycol monomethyl ether acetate (PGMEA). Thereafter, the liquid mixture was heated to 70° C. and stirred for 5 hours for polymerization to obtain a copolymer A1-1 having a solids content of 31% by weight. The copolymer A1-1 thus prepared had a weight average molecular weight of 12,000 Da, an acid value of 100 mg KOH / g, and a polydispersity (Mw / Mn) of 2.80.
preparation example 2
t Copolymer (A1-2)
[0249]The same procedures as in Preparation Example 1 were carried out to prepare a copolymer A1-2 having a solids content of 31% by weight, except that the kinds and contents of the monomers were changed as shown in Table 1 below. The copolymer A1-2 thus prepared had a weight average molecular weight of 14,000 Da, an acid value of 100 mg KOH / g, and a polydispersity (Mw / Mn) of 2.48.
preparation example 3
nd Copolymer (A2-1)
[0250]The same procedures as in Preparation Example 1 were carried out to prepare a copolymer A2-1 having a solids content of 31% by weight, except that the kinds and contents of the monomers were changed as shown in Table 2 below. The copolymer A2-1 thus prepared had a weight average molecular weight of 14,100 Da, an acid value of 100 mg KOH / g, and a polydispersity (Mw / Mn) of 3.23.
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