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Ink compositions

Inactive Publication Date: 2005-01-04
XEROX CORP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Benefits of technology

The inks of the present invention possess excellent dry and wet smear resistance, that is a dry smear optical density of at least less than about 0.10, more generally a dry smear optical density of preferably from about 0 to about 0.07. (the less OD values for smear indicate less transfer onto people). The OD smear is a measure of how much ink or developed image can be removed from the original image as compared with a print image of the same ink without the polyurethane resin. The wet smear optical density of the inks is at least about 0.20, and more generally the wet smear optical density is about 0.10, and preferably from about 0 to about 0.10. The advantage to reduction in smear is that the productivity of the output of prints can be increased, when the smear is reduced. If reduced, the page to page contact is unaffected by smeared images on the backside of pages. Also, less of the image would be transferred to people's fingers etc. Another advantage, is possibly for highlighter smearing. Less smear would enable less transfer when a highlighter pen is drawn across the image, or when liquids are spilled and wiped up.

Problems solved by technology

As the bubble begins to collapse, the ink remaining in the channel between the nozzle and bubble starts to move toward the collapsing bubble, causing a volumetric contraction of the ink at the nozzle and resulting in the separation from the nozzle of the bulging ink as a droplet.
Dye-based ink jet inks suffer from deficiencies in waterfastness and lightfastness after being printed on various substrates.
Some cosolvents that can be selected as clogging inhibitors cause destabilization of pigment dispersions and, therefore, are not usually effective in pigmented inks.

Method used

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Examples

Experimental program
Comparison scheme
Effect test

example ia

An ink comprised of 3 percent by weight of CABOT IJX56 carbon black obtained from Cabot Corporation, 22 percent by weight of sulfolane (obtained from Bayer), 6 percent by weight of 2-pyrrolidinone, 0.05 percent by weight of polyethyleneoxide (M.sub.w =18,500 grams / mole) (obtained from Polysciences), and 1 percent by weight of the polyurethane resin emulsion of Example I (the emulsion was comprised of 41 percent by weight of polyurethane resin, 0.5 percent by weight IGEPAL CO-850 .TM. (nonylphenol ethoxylate), and 58.5 percent by weight of water) was prepared by dissolution of the polyethyleneoxide in water through simple agitation using a stir bar for about 5 minutes, followed by the addition of sulfolane, 2-pyrrolidinone and the polyurethane resin emulsion. This mixture was added to a stirring solution of CABOT IJX56 carbon black. The ink mixture was stirred with a stir bar for about 5 to about 10 minutes, and the resulting ink mixture was filtered through a 1 .mu.m glass fiber fil...

example ib

An ink comprised of 3 percent by weight of CABOT IJX56 carbon black obtained from Cabot Corporation, 22 percent by weight of sulfolane (obtained from Bayer), 6 percent by weight of 2-pyrrolidinone, 0.05 percent by weight of polyethyleneoxide (M.sub.w =18,500 grams / mole) (obtained from Polysciences), and 3.5 percent by weight of the polyurethane resin emulsion of Example I (the emulsion was comprised of 41 percent by weight of polyurethane resin, 0.5 percent by weight IGEPAL CO-850.TM. (nonylphenol ethoxylate), and 58.5 percent by weight of water) was prepared by dissolution of the polyethyleneoxide in water through simple agitation using a stir bar for about 5 minutes, followed by the addition of sulfolane, 2-pyrrolidinone and the polyurethane resin emulsion. This mixture was added to a stirring solution of CABOT IJX56 carbon black. The ink mixture was stirred with a stir bar for about 5 to about 10 minutes, and the resulting ink mixture was filtered through a 1 .mu.m glass fiber fi...

example ii

A polyester polyurethane resin emulsion was prepared as follows:

(A) Preparation of a polyester-polyol:

In a 5 liter jacketed glass flask equipped with a mechanical stirrer, 2,056 grams of phthalic anhydride, 346 grams of stearic acid, 535 grams of trimethylolpropane, 1,000 grams of neopentyl glycol, and 567 grams of 1,6-hexanediol were added. The mixture was heated at 210.degree. C. for 6 hours and condensed until the acid number was about 3. The resulting polester polyol had a hydroxyl number of 158.

(B) Preparation of a polyester polyurethane resin emulsion:

In a 5 liter jacketed glass flask equipped with a mechanical stirrer, 1,053 grams of the above prepared polyester polyol, 50 grams of dimethylolpropionic acid, 188 grams of xylene, and 1.6 grams of tin(II) octanoate were homogenized at 5,000 rpm at 90.degree. C. for 30 minutes. Then 148 grams of a mixture containing 80 weight percent of 1-methyl-2,4-diisocyanatocyclohxane and 20 weight percent of 1-methyl-2,6-diisocyanatocyclohex...

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Abstract

A process for the preparation of an ink which comprises mixing an ink vehicle, a colorant and a polyurethane resin emulsion.

Description

PENDING APPLICATIONS AND PATENTSDisclosed in U.S. Pat. No. 5,837,043 and U.S. Pat. No. 5,762,695 the disclosures of each patent being totally incorporated herein by reference in their entirety, are inks with certain surfactants. More specifically, in U.S. Pat. No. 5,762,695, there is disclosed an ink jet ink and imaging process which comprises the development of an image with an aqueous ink jet ink composition comprised of colorant, water, and a polyhydroxy alcohol surfactant present in an amount of from about 2 to about 10 weight percent.The following patents, the disclosures of each being totally incorporated herein by reference relate to ink jet inks:U.S. Pat. No. 5,973,026 relating to an aqueous ink containing a dissipatible polymer, colorant and a zwitterionic component like betaine;U.S. Pat. No. 5,977,209 relating to an ink containing a colorant, polymer, such as a dissipatible polymer, vehicle, and a salt of polyacrylic, a salt of polyamic acid, a salt of alginic acid, or mix...

Claims

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Application Information

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IPC IPC(8): C09D11/00
CPCC09D11/30
Inventor NICHOLS, GARLAND J.CHENG, CHIEH-MINFU, MIN-HONGKNEISEL, ELIZABETH A.
Owner XEROX CORP
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