Ink compositions
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example ia
An ink comprised of 3 percent by weight of CABOT IJX56 carbon black obtained from Cabot Corporation, 22 percent by weight of sulfolane (obtained from Bayer), 6 percent by weight of 2-pyrrolidinone, 0.05 percent by weight of polyethyleneoxide (M.sub.w =18,500 grams / mole) (obtained from Polysciences), and 1 percent by weight of the polyurethane resin emulsion of Example I (the emulsion was comprised of 41 percent by weight of polyurethane resin, 0.5 percent by weight IGEPAL CO-850 .TM. (nonylphenol ethoxylate), and 58.5 percent by weight of water) was prepared by dissolution of the polyethyleneoxide in water through simple agitation using a stir bar for about 5 minutes, followed by the addition of sulfolane, 2-pyrrolidinone and the polyurethane resin emulsion. This mixture was added to a stirring solution of CABOT IJX56 carbon black. The ink mixture was stirred with a stir bar for about 5 to about 10 minutes, and the resulting ink mixture was filtered through a 1 .mu.m glass fiber fil...
example ib
An ink comprised of 3 percent by weight of CABOT IJX56 carbon black obtained from Cabot Corporation, 22 percent by weight of sulfolane (obtained from Bayer), 6 percent by weight of 2-pyrrolidinone, 0.05 percent by weight of polyethyleneoxide (M.sub.w =18,500 grams / mole) (obtained from Polysciences), and 3.5 percent by weight of the polyurethane resin emulsion of Example I (the emulsion was comprised of 41 percent by weight of polyurethane resin, 0.5 percent by weight IGEPAL CO-850.TM. (nonylphenol ethoxylate), and 58.5 percent by weight of water) was prepared by dissolution of the polyethyleneoxide in water through simple agitation using a stir bar for about 5 minutes, followed by the addition of sulfolane, 2-pyrrolidinone and the polyurethane resin emulsion. This mixture was added to a stirring solution of CABOT IJX56 carbon black. The ink mixture was stirred with a stir bar for about 5 to about 10 minutes, and the resulting ink mixture was filtered through a 1 .mu.m glass fiber fi...
example ii
A polyester polyurethane resin emulsion was prepared as follows:
(A) Preparation of a polyester-polyol:
In a 5 liter jacketed glass flask equipped with a mechanical stirrer, 2,056 grams of phthalic anhydride, 346 grams of stearic acid, 535 grams of trimethylolpropane, 1,000 grams of neopentyl glycol, and 567 grams of 1,6-hexanediol were added. The mixture was heated at 210.degree. C. for 6 hours and condensed until the acid number was about 3. The resulting polester polyol had a hydroxyl number of 158.
(B) Preparation of a polyester polyurethane resin emulsion:
In a 5 liter jacketed glass flask equipped with a mechanical stirrer, 1,053 grams of the above prepared polyester polyol, 50 grams of dimethylolpropionic acid, 188 grams of xylene, and 1.6 grams of tin(II) octanoate were homogenized at 5,000 rpm at 90.degree. C. for 30 minutes. Then 148 grams of a mixture containing 80 weight percent of 1-methyl-2,4-diisocyanatocyclohxane and 20 weight percent of 1-methyl-2,6-diisocyanatocyclohex...
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