The invention discloses a back silver paste for double-sided PERC solar cells. The composition and mass percentage of the paste are: 35-50% of a first-class spherical silver powder, 5-20% of a second-class spherical silver powder, 0.5-50% 5% glass powder, 35-50% organic binder, 4-10% thixotropic agent, 0.5-5% auxiliary agent, 0.01-2% inorganic additive, and the inorganic additive is CaSiO 3 、Al 2 (SiO 3 ) 3 , gas phase SiO 2 、Al 2 o 3 , SiNx, and in the process of preparing the slurry, the inorganic additive and the glass powder are ball-milled, mixed and coated, and then mixed with other components of the slurry to make a slurry. In the present invention, by selecting inorganic powdery additives with good affinity with silicon wafers, they can be attached to the surface of silicon wafers during sintering, have a certain barrier effect on the contact between glass powder and silicon wafers, and slow down the impact of glass powder on silicon wafers during the melting process. The erosion speed is high, and the open circuit voltage is increased; the inorganic additive is mixed with the glass powder in advance, which can realize the precise barrier of the glass powder and improve the barrier efficiency of the inorganic additive.