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Method for preparing bright yellow active dye stuff K-6G

A reactive dye, bright yellow technology, applied in reactive dyes, dyeing methods, azo dyes, etc., can solve the problems of color supply, color fixation rate, low solubility, poor chlorine bleaching fastness, etc., to achieve excellent color supply, Eliminate the discharge of sewage, the effect of improvement and color fixing rate

Inactive Publication Date: 2008-02-13
泰州市姜堰区东风染料化工厂
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

The fastness to chlorine bleaching is poor, so it is not suitable for fabrics that require chlorine bleaching or high chlorine bleaching resistance after dyeing. It can also be used for printing, and the products produced by the salting out process have low color yield, color fixation rate and solubility.

Method used

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  • Method for preparing bright yellow active dye stuff K-6G
  • Method for preparing bright yellow active dye stuff K-6G
  • Method for preparing bright yellow active dye stuff K-6G

Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] 1. Ingredients list:

[0032] raw material name

Molecular weight

Molecular ratio

100% discount (kg)

Feeding amount (mole)

Cyanuric chloride

2,4-Diaminobenzene sulfonate sodium

Sodium Nitrite

Hydrochloric acid

3-formylamino-4-methyl-6-

Hydroxy-N-Ethylpyridone

Sodium p-sulfanilic acid

184.5

210.2

69.01

36.5

196

173.2

1.0

0.9584

0.9802

3.2

0.949

1.05

149.25

162.97

54.72

94.48

150.47

147.1

0.80894

0.80894

0.80894

0.80894

0.80894

0.80894

[0033] 2. The K-6G preparation process of the present invention operates as follows:

[0034] a. Dissolution of sodium 2,4-diaminobenzene sulfonate

[0035] Put 2000L of bottom water in the dissolving pot, add 162.97kg of sodium 2,4-diaminobenzenesulfonate, stir to clarify, adjust the pH=5.5 with dilute hydrochloric acid, the temperature is 18℃, the v...

Embodiment 2

[0058] a. Dissolution of sodium 2,4-diaminobenzene sulfonate

[0059] Put 2000L of bottom water in the dissolving pot, add 162.97kg of sodium 2,4-diaminobenzenesulfonate, stir to clarify, adjust pH to 6.0 with dilute hydrochloric acid, temperature to 20°C, volume to 3200L, C%=7 in the solution.

[0060] b. The first condensation reaction: add 200L of water and crushed ice to a shrinkage, cast weight content of industrial product 99.5% cyanuric chloride 150kg, beating for 45 minutes, adjust pH=2.5 with dilute hydrochloric acid, temperature 5℃, Add the sodium 2,4-diaminobenzene sulfonate solution to a shrinking pot within 2 hours, stir and react for 2 hours after the addition, and control the temperature of the solution at 8°C after the reaction.

[0061] c. Neutralization and acidification

[0062] Quickly add 10% soda ash water within 10 minutes to adjust the pH of the product to 6.5, stabilize for 2 minutes, add crushed ice, quickly add hydrochloric acid, increase the volume of 4...

Embodiment 3

[0074] a. Dissolution of sodium 2,4-diaminobenzene sulfonate

[0075] Put 2000L of bottom water in the dissolving pot, add 162.97kg of sodium 2,4-diaminobenzenesulfonate, stir to clarify, adjust pH=5.0 with dilute hydrochloric acid, temperature 15℃, volume 3200L, C%=6 in the solution.

[0076] b. The first condensation reaction: add 200L of water and crushed ice to a shrinkage, cast weight content of industrial product 99.5% cyanuric chloride 150kg, beating for 45 minutes, adjust pH=1.5 with dilute hydrochloric acid, temperature is 0℃, And in 1.5 hours, add 2,4-diaminobenzene sulfonate sodium solution to a shrinking pot, and after the addition, the reaction was stirred for 2 hours, and the temperature of the solution was controlled at 2°C after the reaction.

[0077] c. Neutralization and acidification

[0078] Quickly add 10% soda ash water within 10 minutes to adjust the pH of the product to 5.5, stabilize for 2 minutes, add crushed ice, quickly add hydrochloric acid, increase t...

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PUM

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Abstract

The related preparation method for bright-yellow reactive dyes K-6G for dyeing and printing to cotton, hair, silk, leather, polyamide synthetic fabric and other fibre mix-fabric comprises: with 2, 4-sodium biaminobenzoic sulfonate, cyanuric chloride, NaNO2, HCl, 3-carbamoyl-4-methyl-6- hydroxyl-N-acetaldehydepyridone, and sodium p-anilinesulfonate as materials; dissolving, first condensing, neutralizing, coupling, second condensing, spray drying, blending, and obtaining the target. This invention can reduce pollution and cost, and has high yield fit to industrial production.

Description

Technical field [0001] The invention relates to a preparation method of a bright yellow reactive dye K-6G suitable for dyeing and printing cotton, wool, silk, leather, polyamide synthetic fiber and other blended fiber fabrics. Background technique [0002] Reactive dyes have outstanding characteristics such as bright color, excellent application performance, convenient use and strong applicability. In the past 20 years, due to environmental and ecological constraints and economic factors, the requirements for the production and preparation of reactive dyes, dye uptake, fixation rate, and dyeing wastewater have become higher and higher. In patent applications related to reactive dyes, the salting out The preparation process is no longer common, and the research and development of reactive dyes in various countries has evolved from the salting-out process to the spray drying process. At present, there is a bright yellow reactive dye whose molecular structure is shown in formula I: ...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C09B62/51D06P1/38D06P3/60D06P3/14D06P3/32D06P3/24
Inventor 戴春林陈才美李兴喜
Owner 泰州市姜堰区东风染料化工厂
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