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Polyesterglycol, adhesive of polyurethane and decorating plate of aluminum with high light film being covered

A polyurethane adhesive and polyester diol technology, applied in the field of adhesives, can solve problems such as relatively high energy consumption, unsuitability for conventional lamination processes and equipment, and short storage period

Inactive Publication Date: 2008-07-09
上海理日化工新材料有限公司
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

However, the coating temperature of this type of coating adhesive is as high as 200-230 ° C, relatively high energy consumption and short storage period, only about 3 months
This kind of laminating adhesive is difficult to apply to heat-sensitive materials, and it is not suitable for conventional laminating processes and equipment

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0054] Add 124.2 grams of dimethyl terephthalate, 324 grams of 1,4-butanediol and n-ethyl titanate to a 1000-ml three-necked flask equipped with a thermometer, a mechanical stirrer, a Vigger fractionation column and a condenser. Esters 0.23 g. Heating to raise the temperature, when the temperature in the bottle reaches 100°C, the material begins to melt, then start stirring. When the temperature rises to about 145°C, methanol droplets begin to distill out, and the temperature continues to rise until the temperature in the bottle reaches about 200°C. When methanol is distilled out close to 41 grams, when the theoretical amount is reached, the transesterification reaction is completed, and the heating is stopped and cooled.

[0055] When the internal temperature of the above-mentioned three-necked flask drops below 100°C, add 99.6 grams of isophthalic acid, 153.5 grams of sebacic acid, and 0.2 grams of triphenyl phosphite, then stir and heat up, when the internal temperature ri...

Embodiment 2

[0059] Add 174.6 grams of dimethyl terephthalate, 288 grams of 1,4-butylene glycol, and 84.8 grams of diol and 0.23 grams of n-ethyl titanate. Heating to raise the temperature, when the temperature in the bottle reaches 100°C, the material begins to melt, then start stirring. When the temperature rises to about 145°C, methanol droplets begin to distill out, and the temperature continues to rise until the temperature in the bottle reaches about 200°C. Treat to distill out methyl alcohol close to 58 grams, when reaching theoretical amount, transesterification reaction is finished, stops heating, cools down.

[0060] When the internal temperature of the above-mentioned three-necked flask drops below 100°C, add 99.6 grams of isophthalic acid, 73 grams of adipic acid, and 0.2 grams of triphenyl phosphite, then stir and heat up, when the internal temperature rises to about 160°C , with water distilling out, continue to heat up to about 210°C. The amount of water distilled is clos...

Embodiment 3

[0064] Add 174.6 grams of dimethyl terephthalate, 432 grams of 1,4-butanediol, and 74.4 grams of ethylene glycol in a 1000-milliliter three-necked flask equipped with a thermometer, a mechanical stirrer, a Vigre column and a condenser. gram and 0.31 gram of n-butyl titanate. Heating to raise the temperature, when the temperature in the bottle reaches 100°C, the material begins to melt, then start stirring. When the temperature rises to about 148°C, methanol droplets begin to distill out, and the temperature continues to rise until the temperature in the bottle reaches about 200°C. Treat to distill out methyl alcohol close to 58 grams, when reaching theoretical amount, transesterification reaction is finished, stops heating, cools down.

[0065] When the internal temperature of the above-mentioned three-necked flask drops below 100°C, add 149.4 grams of isophthalic acid, 175.2 grams of adipic acid, and 0.25 grams of triphenyl phosphite, then stir and raise the temperature. Whe...

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Abstract

This invention relates to a polyester glycol, which is condensation polymerized from: a) dicarboxylic acid component comprising terephthalic acid, isophthalic acid and C6~12 aliphatic dicarboxylic acid units, and b) glycol component. The mole ratio between terephthalic acid, isophthalic acid and C6~12 aliphatic acid units is 1: (0.60~1.30): (0.50~1.70) and the weight-average molecular weight of the polyester glycol is 27000~37500. When mixed with polyisocyanate curing agent, such a polyester glycol is changed into polyurethane adhesive, which is applicable in manufacturing highlight-coated aluminium decorative plates with both a low coating temperature and high peel strength.

Description

field of invention [0001] The invention relates to an adhesive, especially a polyurethane adhesive used for manufacturing a high-gloss film-coated aluminum decorative board, a polyester diol used for preparing the polyurethane adhesive, and a high-gloss coated aluminum decorative board made of the polyurethane adhesive. Background technique [0002] High-gloss coated aluminum decorative panels are currently the ceiling materials for high-end cabinets and bathrooms. The current coating adhesives are all one-component polyurethane adhesives. However, the film temperature of this film-coated glue is as high as 200-230°C, relatively high energy consumption and short storage period, only about 3 months. This laminating adhesive is difficult to apply to heat-sensitive materials, and is not suitable for conventional laminating processes and equipment. Contents of the invention [0003] The object of the present invention is to provide a low-melting point polyester diol and a two...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): C08G63/181C09J175/06C08J5/12
Inventor 蔡真何文详黄永生
Owner 上海理日化工新材料有限公司