Colored composition for color filters, color filter and liquid crystal display device
A technology for coloring compositions and color filters, which can be applied in the directions of instruments, filters, optics, etc., can solve the problems of insufficient color reproduction area in expanding liquid crystal display devices, etc.
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Embodiment 1
[0191] A mixture of the following compositions was uniformly stirred and mixed, and then filtered through a 1 μm filter to obtain an alkali-developing type cyan coloring composition 1 .
[0192] Pigment dispersion 1 shown in Table 2 12.0 parts
[0193] Pigment dispersion 9 shown in Table 2 48.0 parts
[0194] Photopolymerization initiator 2.0 parts
[0195] ("IRGACURE" 907 manufactured by Ciba Specialty Chemicals)
[0196] Trimethylolpropane triacrylate 5.0 parts
[0197] ("NK ESTER ATMPT" produced by Shin-Nakamura Chemical Co., Ltd.)
[0198] 0.5 parts of sensitizer
[0199] ("EAB-F" produced by Hodo Keya Chemical Co., Ltd.)
[0200] Acrylic resin solution 1 2.5 parts
[0201] Cyclohexanone 30.0 parts
Embodiment 2-20、 comparative example 1-3
[0203] Except using the pigment dispersion shown in Table 3, following the same method as Example 1, cyan or yellow coloring composition 2-20 was obtained.
[0204]
[0205] Coloring compositions 16-19 were obtained in the same manner as in Example 1 except that the pigment dispersions shown in Table 3 were used.
[0206] table 3
[0207]
coloring composition
Hue of the coloring composition
type
Quantity (parts)
type
Quantity (parts)
x
y
Y
Example 1
1
1
12
9
48
0.131
0.222
12.8
1500
2.7
Example 2
2
2
12
9
48
0.131
0.222
12.9
2000
2.9
Example 3
3
4
12
9
48
0.131
0.222
12....
Embodiment 11-24、 and comparative example 4-6
[0221]
[0222] A black matrix is processed to form a pattern on a glass substrate, and a coloring composition 17 is applied on the substrate with a spin coater to form a coating film of the coloring composition. Irradiate 300mJ / cm with an ultra-high pressure mercury lamp through a photomask on the film 2 of ultraviolet light. Next, the unexposed part was removed by spray development with an alkaline developer composed of 2% by weight of sodium carbonate aqueous solution, and then washed with ion-exchanged water, and the substrate was heated at 230°C for 20 minutes to form a film thickness of 2.5 μm. red filter section. In the same manner, green filter segments and blue filter segments having a film thickness of 2.5 μm were formed using coloring compositions 18 and 19 . In the same manner, coloring compositions 1-27 shown in Table 5 were used to form cyan, yellow, and magenta filter segments with a film thickness of 2.5 μm to produce color filters.
[0223]
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