Phase change memory unit with loop phase change material and its making method
A technology of phase-change memory and phase-change materials, which is applied in the field of micro-nano electronics and can solve problems such as differences in device structure preparation methods
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Embodiment 1
[0043] The preparation process of the phase change memory device unit prepared by utilizing the annular phase change material according to the present invention is as follows:
[0044] Step 1: The substrate is a silicon wafer, and a layer of SiO is prepared on the silicon wafer by thermal oxidation 2 The first insulating material layer has a film thickness of 500nm. (figure 1)
[0045] Step 2: On SiO 2 On the first insulating material layer, the lower electrode W thin film is prepared by magnetron sputtering method, and the process parameters are: the background pressure is 1×10 -4 Pa, the Ar gas pressure during sputtering is 0.08Pa, the sputtering power is 400W, the substrate temperature is 25°C, and the film thickness is 100nm. (figure 2)
[0046] Step 3: Prepare SiO on W film by magnetron sputtering 2 For the second insulating film layer, the process parameters are: the background air pressure is 1×10 -4 Pa, the Ar gas pressure during sputtering is 0.12Pa, the sputter...
Embodiment 2
[0056] Change step 5 in embodiment 1 as follows: in SiO 2 Preparation of heat insulating material SiO by PECVD method on heat insulating film and TiN heating electrode material 2 Thin film, the thickness of the film is 200nm; then, conventional photolithography technology is used to expose and etch directly above the heating electrode TiN to prepare a circular hole with a diameter of 200nm, and the heating electrode TiN is exposed in the hole.
[0057] Change step 7 in Example 1 to the following: Reactive ion etching technology is used to etch and remove the phase change material at the bottom of the circular hole to form a ring-shaped phase change material with an outer diameter of 200 nm and a wall thickness of 10 nm.
[0058] The rest of the steps are exactly the same as in Example 1, and a phase change memory device unit whose outer diameter of the annular phase change material is smaller than that of the heating electrode material can be prepared. (Figure 11)
Embodiment 3
[0060] Change step 5 in embodiment 1 as follows: in SiO 2 Preparation of heat insulating material SiO by PECVD method on heat insulating film and TiN heating electrode material 2 Thin film, the thickness of the film is 200nm; then, conventional photolithography technology is used to expose and etch directly above the heating electrode TiN to prepare a circular hole with a diameter of 350nm, and the heating electrode TiN is exposed in the hole.
[0061] Change step 6 in embodiment 1 as follows: adopt atomic layer deposition technology to prepare Ge in the hole 2 Sb 2 Te 5 Phase change material with a film thickness of 40nm.
[0062] Change step 7 in Example 1 to the following: Reactive ion etching technology is used to etch and remove the phase-change material at the bottom of the circular hole to form a ring-shaped phase-change material with an outer diameter of 350 nm and a wall thickness of 40 nm.
[0063] The rest of the steps are exactly the same as in Example 1, and a...
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