Organic electrically stimulated photo emission material and organic electrically stimulated photo emission element
An electroluminescence element and electroluminescence technology are applied in the direction of luminescent materials, electroluminescence light sources, electrical components, etc., which can solve the problems of general products without structure, unable to use blue phosphorescent materials, and insufficient energy levels, etc., to achieve Effect of increasing luminous efficiency and thermal stability
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no. 1 example
[0058] The organic electroluminescence material according to the first embodiment of the present invention has the structure of the following formula (1),
[0059]
[0060] Formula 1)
[0061] where X 1 Oxygen atom, sulfur atom or NH, Y 1 with Z 1 Is independently nitrogen atom, alkyl (alkyl), haloalkyl or cycloalkyl (cycloalkyl), R 1 to R 4 is independently hydrogen, alkyl (alkyl), haloalkyl, cycloalkyl (cycloalkyl) or alkoxyl (alkyloxy), R 5 For aromatic (aromatic rings), R 6 is hydrogen, alkyl, haloalkyl, cycloalkyl, alkoxy or
[0062]
[0063] where X 2 Oxygen atom, sulfur atom or NH, Y 2 with Z 2 Is independently nitrogen atom, alkyl (alkyl), haloalkyl or cycloalkyl (cycloalkyl), R 7 to R 10 is independently hydrogen, alkyl (alkyl), haloalkyl, cycloalkyl (cycloalkyl) or alkoxyl (alkyloxy), R 11For aromatic (aromatic rings).
[0064] Herein, R 1 , R 2 , R 3 , R 4 , R 6 , R 7 , R 8 , R 9 with R 10 are independently substituted alkyl groups with 1...
no. 2 example
[0070] As shown in FIG. 2, the organic electroluminescent element 2 according to the second embodiment of the present invention is arranged on a substrate 21, and includes a first electrode 22, a light-emitting layer 23 and a second electrode 24 in sequence, and the light-emitting layer 23 contains at least one organic electroluminescent material, and the organic electroluminescent material has the structure of the following formula (2),
[0071]
[0072] Formula (2)
[0073] where X 3 Oxygen atom, sulfur atom or NH, Y 3 with Z 3 Is independently nitrogen atom, alkyl (alkyl), haloalkyl or cycloalkyl (cycloalkyl), R 12 to R 15 is independently hydrogen, alkyl (alkyl), haloalkyl, cycloalkyl (cycloalkyl) or alkoxyl (alkyloxy), R 16 For aromatic (aromatic rings), R 17 is hydrogen, alkyl, haloalkyl, cycloalkyl, alkoxy or
[0074]
[0075] where X 4 Oxygen atom, sulfur atom or NH, Y 4 with Z 4 Is independently nitrogen atom, alkyl (alkyl), haloalkyl or cycloalkyl (cy...
experiment example 1
[0110]
[0111]Compound 2: (N', N"-di(benzoyl)diphenylic acid hydrazide) Take compound 1 (10.0g) into a double-neck flask (500mL), and inject toluene and ethanol (each 40mL). Under nitrogen atmosphere with Stir with a magnetic stirrer, then inject NH 2 NH 2 ·H 2 O (15 mL) and then heated to 105 °C. And after maintaining for 24 hours, distill the solvent and residual NH 2 NH 2 After removal, a white solid precipitated out. After adding ethanol to wash the white solid, the white solid was collected by suction filtration, and finally the residual solvent was removed from the white solid with a mechanical pump to obtain the product (8.3 g), with a yield of 82.3%.
[0112] The above-mentioned white solid (15.00 g, 55.49 mmol) was put into a double-necked bottle (250 ml), nitrogen gas was passed through one end, and the other end was sealed with a serum stopper. Pour dehydrated NMP (150ml) and stir with a magnetic stirring bar. After ice bathing for 20 minutes, Benzoyl chl...
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Abstract
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