Copolymerization type intrinsic conductive polymer and method for preparing same
An intrinsically conductive and polymer technology, applied in the field of intrinsically conductive polymers and their preparation, copolymerized intrinsically conductive polymers and their preparation, can solve the problems of complex preparation process, difficult processing, and oxidation resistance of products, etc. To achieve a promising effect
- Summary
- Abstract
- Description
- Claims
- Application Information
AI Technical Summary
Problems solved by technology
Method used
Image
Examples
Embodiment 1
[0025] Embodiment 1: use bismuth reagent I and methyl methacrylate copolymerization
[0026] Put bismuth reagent I (Shanghai Zhixin Chemical Co., Ltd.) and methyl methacrylate in equimolar proportions into a reactor with a constant temperature device filled with ethanol. The volume of ethanol is the volume of bismuth reagent I and methyl methacrylate. Keep the temperature at 20°C, stir to fully dissolve, then add ferric chloride solution dissolved in ethanol, add concentrated sulfuric acid dropwise while stirring, keep the total acidity of the reaction mixture at 0≤pH≤1, 30 minutes Finally, the reaction mixture was suction-filtered with a Buchner funnel, washed three times with ethanol, and dried under vacuum at 45° C. to obtain a light yellow solid powder, which is a copolymerized intrinsically conductive polymer.
[0027] In the above-mentioned reaction, the amount of bismuth reagent I and methyl methacrylate accounts for 9% of the total moles of the reactants, the amount of...
Embodiment 2
[0029] Embodiment 2: use bismuth reagent I and ethyl methacrylate copolymerization
[0030] Put bismuth reagent II (Shanghai Zhixin Chemical Co., Ltd.) and ethyl methacrylate in equimolar proportions into a reactor with a constant temperature device filled with ethanol. The volume of ethanol is the volume of bismuth reagent II and ethyl methacrylate. Keep the temperature at 25°C, stir to fully dissolve, then add ferric chloride solution dissolved in ethanol, add concentrated sulfuric acid dropwise while stirring, keep the total acidity of the reaction mixture at 0≤pH≤1, 60 minutes Finally, the reaction mixture was sucked out with a Buchner funnel, washed 5 times with ethanol, and vacuum-dried at 50° C. to obtain a light yellow solid powder, which is a copolymerized intrinsically conductive polymer.
[0031] In the above-mentioned reaction, the amount of bismuth reagent II and ethyl methacrylate accounts for 10% of the total moles of the reactants, the amount of ferric chloride...
Embodiment 3
[0033] Embodiment 3: use bismuth reagent I and bismuth reagent II and ethyl methoxyacrylate copolymerization
[0034]Put bismuth reagent I, bismuth reagent II (Shanghai Zhixin Chemical Co., Ltd.), methyl methoxyacrylate into a reactor with a constant temperature device filled with ether in a molar ratio of 1:5:1, and the volume of ether is Bismuth reagent I, bismuth reagent II and methyl methacrylate mixture are 3 times the total volume, keep the temperature at 30°C, stir to make it fully dissolved, then add ferric chloride solution dissolved in ethanol, and add concentrated Sulfuric acid to keep the total acidity of the reaction mixture at pH = 1. After 50 minutes, filter the reaction mixture with a Buchner funnel, wash it with ethanol three times, and dry it in vacuum at 55°C to obtain a light yellow solid powder, which is the copolymerization type Intrinsically conducting polymers.
PUM
| Property | Measurement | Unit |
|---|---|---|
| electrical conductivity | aaaaa | aaaaa |
| thermal decomposition temperature | aaaaa | aaaaa |
Abstract
Description
Claims
Application Information
Login to View More