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Fluidizer and technique for preparing ethylene by ethanol dehydration

A technology of ethanol dehydration and fluidization equipment, which is applied in the field of equipment for preparing hydrocarbons from non-hydrocarbon compounds, which can solve the problems of reduced ethylene purity and increased side reactions, and achieve the effect of improved purity and optimal heat balance

Active Publication Date: 2008-10-01
CHINA PETROLEUM & CHEM CORP +1
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  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

[0010] The main problem of using a fluidized bed reactor for ETE is that the regenerated catalyst entrains flue gas, which contains a large amount of impurity gases such as nitrogen, oxygen, carbon dioxide, carbon monoxide, etc., and the regenerated catalyst entrained with flue gas returns to the fluidized bed for reaction The device will increase the side reaction and greatly reduce the purity of ethylene in the product, requiring expensive cryogenic separation to improve its purity

Method used

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  • Fluidizer and technique for preparing ethylene by ethanol dehydration
  • Fluidizer and technique for preparing ethylene by ethanol dehydration

Examples

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Embodiment

[0041] The relevant tests in the examples were carried out on a medium-sized device integrating ethanol dehydration to ethylene (ETE) and catalytic cracking (FCC) controlled in real time by a computer. The processing capacity of this device is 0.4t / d, and the raw material is 5% water content The ethanol, the feed rate of ethanol is, the weight hourly space velocity is 1.2h -1 , the fluidized bed reaction temperature is 380°C, and the reaction pressure is 0.2MPa. The catalyst is FCC catalyst GOR-2 catalyst (800° C., 100% steam aging for 17 hours) developed by Sinopec Petrochemical Research Institute.

[0042] The product distribution is shown in Table 1. From Table 1, it can be seen that the conversion rate of ethanol is 99.6%, and the purity of ethylene is as high as 99.0v%.

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Abstract

The invention relates to a fluidized device for producing ethylene by ethanol dehydration, which comprises a fluidized bed reactor, a regenerator, a catalyst riser, a stripper and a regenerated catalyst degassing tank, wherein, the stripper and the regenerator are connected by spent catalyst conveying pipes, the fluidized bed reactor and the catalyst riser are connected directly, the regenerated catalyst degassing tank and the regenerator are connected by regenerated catalyst conveying pipes, the regenerated catalyst degassing tank and the catalyst riser are connected by the regenerated catalyst conveying pipes and an external heat collector is positioned in the regenerated catalyst degassing tank. The fluidized device, through adding the regenerated catalyst degassing tank, effectively removes flue gas taken by the regenerated catalyst and greatly improves the purity of ethylene in the product. The regenerator is arranged independently or a catalytic cracking regenerator is shared with a catalytic cracking device in the field of petroleum refining.

Description

technical field [0001] The present invention pertains to an apparatus and method for the preparation of hydrocarbons from a non-hydrocarbon compound, and more particularly to an apparatus and method for the dehydration of an oxygenate to prepare ethylene. Background technique [0002] Ethylene is the most important basic raw material in the petrochemical industry. At present, about 75% of petrochemical products come from ethylene. At present, the world's ethylene production capacity has reached 112.9055 million tons per year, and it is expected that the world's ethylene production capacity will reach 144.455 million tons per year in 2012. In 2010, my country's ethylene equivalent demand is expected to be 25.7 million tons per year, the production capacity is 13.89 million tons per year, and the self-sufficiency rate is only 54%. Therefore, whether it is domestic or foreign, there is still a lot of room for the development of the ethylene market. [0003] There are many ways...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C07C1/24C07C11/04B01J8/24
CPCY02P20/584
Inventor 李强常学良鲁维民杨克勇邢波郭湘波张久顺李家栋龙军舒兴田谢文华吴治国
Owner CHINA PETROLEUM & CHEM CORP
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