Preparation of antistatic water solution

An aqueous, antistatic technology, applied in conductive coatings, coatings, etc., can solve problems such as incompatibility, and achieve the effects of low surface resistance, low equipment requirements, and high visible light transmittance

Inactive Publication Date: 2009-05-20
EAST CHINA UNIV OF SCI & TECH
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

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Problems solved by technology

The product is still not suitable for antistatic coating

Method used

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  • Preparation of antistatic water solution
  • Preparation of antistatic water solution

Examples

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Embodiment 1

[0025] 1) Preparation of poly 3,4 ethylenedioxythiophene / polystyrene sodium sulfonate aqueous solution

[0026] Preparation method: chemical oxidation polymerization

[0027] Reaction temperature: room temperature (15~30℃)

[0028] Planned weighing: potassium persulfate: sodium polystyrene sulfonate: 3,4-ethylenedioxythiophene = 3:5:1

[0029] Solid content of poly-3,4-ethylenedioxythiophene: 1%-1.5%

[0030] PH control: 1-1.5

[0031] Stirring rate: 800R / min

[0032] Actual weighing: Potassium persulfate: 3.1091g, aqueous solution of sodium polystyrene sulfonate: 22.8200g, 3,4-ethylenedioxythiophene: 1.0186g

[0033] Experimental procedure: use an electronic balance to accurately weigh 22.8200g of polystyrene sodium sulfonate aqueous solution and pour it into a three-necked flask, then accurately weigh 1.0186g of 3,4-ethylenedioxythiophene and accurately transfer it into a three-necked flask, then add 150ml of deionized water, magnetically stirred for 10 minutes, and fin...

Embodiment 2

[0045] 1) Preparation of poly 3,4 ethylenedioxythiophene / polystyrene sodium sulfonate aqueous solution

[0046] Preparation method: chemical oxidation polymerization

[0047] Reaction temperature: room temperature (15~30℃)

[0048] Planned weighing: potassium persulfate: sodium polystyrene sulfonate: 3,4-ethylenedioxythiophene=3:2.5:1 poly-3,4-ethylenedioxythiophene solid content: 1%-1.5%

[0049] PH control: 1-1.5

[0050] Stirring rate: 1200R / min

[0051] Actual weighing: Potassium persulfate: 3.1091g, sodium polystyrene sulfonate aqueous solution: 12.5200g, 3,4-ethylenedioxythiophene: 1.0186g

[0052] Experimental procedure: use an electronic balance to accurately weigh 12.5200g of polystyrene sodium sulfonate aqueous solution and pour it into a three-necked flask, then accurately weigh 1.0186g of 3,4-ethylenedioxythiophene and accurately transfer it into a three-necked flask, then add 150ml of deionized water, magnetically stirred for 10 minutes, and finally accurately...

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Abstract

The invention relates to a method for preparing antistatic aqueous solution by the chemical oxypolymerization of 3, 4-ethylenedioxythiophene (EDOT), i.e., potassium peroxydisulfate is used as oxidizer, sodium polystyrene sulfonate aqueous solution is polymerized with the 3, 4-ethylenedioxythiophene and the antistatic aqueous solution with eminent performance is prepared after the most suitable proportion of all the monomers is determined. Being used as a coat, the antistatic aqueous solution prepared by adopting the method of the invention has low surface resistance (1*10<5>Omega/cm<2>), high mechanical strength, high visible light transmittance, and superior electrochemistry performance and thermal stability. The method is simple in operation and has low requirement on equipment.

Description

technical field [0001] The invention relates to a method for preparing an antistatic aqueous solution, in particular to a method for preparing an antistatic aqueous solution by chemical oxidation polymerization of thiophene monomers, that is, chemical oxidation polymerization of 3,4-ethylenedioxythiophene (EDOT). Background technique [0002] Since the discovery of conductive polymers in 1977, countries around the world have set off an upsurge of research on conductive polymers. A large number of studies have shown that various conjugated polymers can become conductive polymers with different conductive properties after doping. Representative conjugated polymers include polythiophene, polypyrrole, polyaniline, and polyparaphenylene. [0003] In the second half of the 1980s, Bayer Corporation of Germany successfully developed a new generation of conductive plastic 3,4-ethylenedioxythiophene (EDOT). It has the following outstanding properties: (1) high electrical conductivit...

Claims

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Application Information

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Patent Type & Authority Applications(China)
IPC IPC(8): C09D125/18C09D5/24C08G61/12C09D165/00
Inventor 汪济奎邱春长茅双明董蓉李冰高磊杨俊郭卫红
Owner EAST CHINA UNIV OF SCI & TECH
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