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Conductive / heat insulating composite material

A composite material and thermosetting technology, applied in the field of fiber reinforced resin matrix composite materials and composite materials, can solve the problems of the influence of the electrical conductivity of the material, reduce the mechanical properties of the material, and not introduce the thermal properties, and achieve the effect of a simple preparation process.

Inactive Publication Date: 2010-10-13
NO 53 RES INST OF CHINA NORTH IND GRP
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  • Summary
  • Abstract
  • Description
  • Claims
  • Application Information

AI Technical Summary

Problems solved by technology

[0004] CN200510062318.3 introduces a preparation method of carbon nanotube / polystyrene nanoconductive composite material, using polystyrene and multi-walled carbon nanotubes as composite matrix, cholate as dispersion medium, and organic solvent as dispersant , the carbon nanotube / polystyrene nanoconductive composite material was prepared by the solution method, and the volume resistivity reached 10 1 Ω.cm, based on the characteristics of polystyrene itself, the heat resistance is poor, and the thermal performance is not introduced
[0005] In order to improve the thermal insulation performance of the material, a large amount of thermal insulation fillers, such as hollow microspheres, etc. are generally added to the material. Performance can also have a significant impact

Method used

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Examples

Experimental program
Comparison scheme
Effect test

Embodiment 1

[0031] Add 8 parts of multi-walled carbon nanotubes (MWNT, Shenzhen Nanometer Port) to a mixed liquid system with a net content of 100 parts of S-157 thermosetting phenolic resin (phenol-formaldehyde resin, produced by Wusan Institute) and 1 part of op-10 , ball milled for 3 hours, soaked 90 parts of hollow glass fiber (Nanjing Glass Fiber Research and Design Institute) with the dispersed glue to make a prepreg. Curing at 40MPa~45MPa, 160℃ for 10 minutes to form a standard composite material, the volume resistivity is 9.5Ω.cm, the thermal conductivity is 0.49W / m.K, and the density is 1.53g / cm 3 .

Embodiment 2

[0033] Mix 10 parts of multi-walled carbon nanotubes (MWNT, Shenzhen Nanometer Port) with a mixture of 100 parts of phenol-cresol formaldehyde resin (Shanghai Xinhua Resin Factory) and 3 parts of DC-193 with a net content of 100 parts, and use a ball mill to grind the carbon nanotubes After dispersing for 3 hours, soak the dispersed glue solution into 120 parts of hollow glass fibers (Nanjing Glass Fiber Research and Design Institute) to make a prepreg. The composite material prepared by curing and molding with a hot press has a volume resistivity of 5.2Ω.cm, a thermal conductivity of 0.49W / m.K, and a density of 1.59g / cm 3 .

Embodiment 3

[0035] Mix 12 parts of multi-walled carbon nanotubes (Tsinghua Nanfeng) with a mixed solution with a net content of 100 parts of resorcinol-formaldehyde resin and 5 parts of op-10, and disperse the carbon nanotubes for 3 hours using a ball mill. 50 parts of hollow quartz fiber (Hubei Feilihua Quartz Glass Co., Ltd.) and 50 parts of hollow glass fiber (Nanjing Glass Fiber Research and Design Institute) were infiltrated with the glue solution to make prepreg. The composite material prepared by curing and molding with a hot press has a volume resistivity of 4.7Ω.cm, a thermal conductivity of 0.49W / m.K, and a density of 1.55g / cm 3 .

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PUM

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Abstract

The invention belongs to the technical field of composite materials, relates to the technical field of fiber-reinforced resin based composite materials, and in particular relates to a composite material with conductive and heat-insulating functions. The conductive / heat-insulating composite material has volume resistivity which is not more than 10 ohm.cm, consists of thermosetting phenolic resin, carbon nanotubes, hollow fibers and surfactant, and is obtained after dispersion of the nanotubes, preparation of a glue solution, preimpregnation of the fibers and curing forming. The conductive / heat-insulating composite material has the advantages of low density, corrosion resistance, superior electrical conductivity, low thermal conductivity and so on, and is a functional material with superiorcomprehensive performance. The functional material not only can meet the use requirements of civilian goods but also can meet the requirements of weapon systems in the national defense fields of weapons, aviation, spaceflight, etc. on the service performance of the material in the severe work environment of high temperature, high overload and so on.

Description

1. Technical field [0001] The invention belongs to the technical field of composite materials, relates to the technical field of fiber-reinforced resin-based composite materials, and particularly relates to composite materials with conductive and heat-insulating functions. 2. Background technology [0002] Composite materials are widely used for their high specific rigidity and strength, and composite materials with conductive or electromagnetic shielding performance have also been developed and successfully applied in recent years. In general, conduction and heat insulation are a pair of contradictions. Materials have good electrical conductivity and good thermal conductivity at the same time. The improvement of material conductivity is often accompanied by the decrease of heat insulation performance. Conductive composite materials mainly include conductive micropowder filling There are two types of resin-based composite materials and fiber-reinforced conductive resin-based...

Claims

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Application Information

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Patent Type & Authority Patents(China)
IPC IPC(8): H01B1/24C08K7/04C08K7/24C08L61/06
Inventor 李莹安振河谢可勇魏化震
Owner NO 53 RES INST OF CHINA NORTH IND GRP
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